The concept of molecular orbital theory in dealing with the resonance concept of benzene and carbonate ion has to be discussed. Concept Introduction: Molecular orbital theory: During the formation of bond, the atomic orbitals of individual atom will combine together to form equal number of molecular orbital. These orbitals are arranged in the order of increasing energy level, while in case of valence bond theory , the individual atomic orbital will directly involve in bond formation. Resonance is the phenomenon of delocalization of pi- electrons through conjugation. The aromaticity in benzene means the extraordinary stability of benzene. The extraordinary stability means the resonance property of benzene.
The concept of molecular orbital theory in dealing with the resonance concept of benzene and carbonate ion has to be discussed. Concept Introduction: Molecular orbital theory: During the formation of bond, the atomic orbitals of individual atom will combine together to form equal number of molecular orbital. These orbitals are arranged in the order of increasing energy level, while in case of valence bond theory , the individual atomic orbital will directly involve in bond formation. Resonance is the phenomenon of delocalization of pi- electrons through conjugation. The aromaticity in benzene means the extraordinary stability of benzene. The extraordinary stability means the resonance property of benzene.
Solution Summary: The author explains the concept of molecular orbital theory in dealing with the resonance concept in benzene and carbonate ion.
Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
Chapter 10, Problem 10.64QP
Interpretation Introduction
Interpretation: The concept of molecular orbital theory in dealing with the resonance concept of benzene and carbonate ion has to be discussed.
Concept Introduction:
Molecular orbital theory:
During the formation of bond, the atomic orbitals of individual atom will combine together to form equal number of molecular orbital. These orbitals are arranged in the order of increasing energy level, while in case of valence bond theory, the individual atomic orbital will directly involve in bond formation.
Resonance is the phenomenon of delocalization of pi- electrons through conjugation. The aromaticity in benzene means the extraordinary stability of benzene. The extraordinary stability means the resonance property of benzene.
Draw the virtual orbitals for the planar and pyramidal forms of CH3 and for the linear and bent forms of CH2
Q2: Draw the molecules based on the provided nomenclatures below:
(2R,3S)-2-chloro-3-methylpentane:
(2S, 2R)-2-hydroxyl-3,6-dimethylheptane:
Q3: Describes the relationship (identical, constitutional isomers, enantiomers or diastereomers)
of each pair of compounds below.
ག
H
CH3
OH
OH
CH3
H3C
OH
OH
OH
//////////
C
CH3
CH3
CH3
CH3
H3C
CH 3
C/III.....
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COOH
H
нош.....
H
2
OH
HO
CH3
HOOC
H
CH3
CH3
CH3
Br.
H
H
Br
and
H
H
H
H
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Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY