A 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0°C. The reaction is 2 Na ( s ) + 2 H 2 O ( l ) → 2 NaOH ( a q ) + H 2 ( g ) Δ H = − 368 kJ Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/g∙°c, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.
A 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0°C. The reaction is 2 Na ( s ) + 2 H 2 O ( l ) → 2 NaOH ( a q ) + H 2 ( g ) Δ H = − 368 kJ Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/g∙°c, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.
Solution Summary: The author explains that the final temperature of an ice has to be calculated.
A 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0°C. The reaction is
2
Na
(
s
)
+
2
H
2
O
(
l
)
→
2
NaOH
(
a
q
)
+
H
2
(
g
)
Δ
H
=
−
368
kJ
Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/g∙°c, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Why do we analyse salt?
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
H
CH3OH, H+
H
Select to Add Arrows
H°
0:0
'H
+
Q
HH
■ Select to Add Arrows
CH3OH,
H*
H.
H
CH3OH, H+
HH
■ Select to Add Arrows i
Please select a drawing or reagent from the question area
Chapter 10 Solutions
WebAssign for Zumdahl/Zumdahl/DeCoste's Chemistry, 10th Edition [Instant Access], Single-Term
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