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Concept explainers
Interpretation:
Increasing order of
Concept introduction:
The following steps are used to determine the molecular shape of the given molecule.
Step 1: Write the Lewis structure of the given formula and place the atoms.
Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.
Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.
Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.
The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In other words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is less or bond angle is more as the number of lone pair decreases on the central atom.
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Chapter 10 Solutions
CHEMISTRY:MOLECULAR...(LL)-W/CONNECT
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. NaO :0: Select to Add Arrows THF > Pleaarrow_forwardapp aktv.com Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. :0: 0:0 H NaO Select to Add Arrows CH3CH2CCNa Problem 31 of 35 Please select aarrow_forwardK Sepp aktiv com Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Drawing Arrows CH3CH2OK, CH3CH2OH Altis Learning App 31 Problem 28 of 35 H. :0: H H H H H 0:0 H KO Undo Reset Donearrow_forward
- Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H_ Br (S) CH 3 H3C (S) H Br A H Br 省 H3C (S) (R) CH₂ Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forward4. Which one of the following is trans-1-tert-butyl-3-methylcyclohexane in its most stable conformation? (NOTE: Correct answer must be trans- and must have a 1,3-arrangement of groups.) C(CH3)3 CH₁₂ A H,C D H₂C C(CH) C(CH3)3 C B CH C(CH) C(CH3)3 Earrow_forwardPredict the Product. Predict the major organic product for the following reaction:arrow_forward
- Nonearrow_forward3. Which one of the following is the lowest energy, most stable conformation of 1-bromopropane? H H H H H H H H CH3 HH Br H CH3 b b b b b CH3 A Br Br H H B CH3 Br H C H H H D CH3 H Br H E Harrow_forwardIn evolution, migration refers to the movement of alleles between populations. In your drawings, compare and contrast migration in evolutionary terms vs. in ecological terms. True Falsearrow_forward
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 31 I 1 :0: O: C 1 1 H Na Select to Add Arrows CH3CH2CCNa 1arrow_forwardgiven asp ...arrow_forwardNonearrow_forward
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