The shape and ideal bond angle around the central atom in ClO 2 − molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained. Concept introduction: The steps to determine the molecular shape of a given molecule are as follows: Step 1: Write the Lewis structure of the given formula and place the atoms. Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement. Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR. Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

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Answer 1

Question

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

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Answer 2

Question

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

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Answer 3

Question

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

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Answer 4

Question

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 6

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 7

Chapter 10, Problem 10.40P

(a)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in ClO2− molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in PF5 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in SeF4 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The shape and ideal bond angle around the central atom in KrF2 molecule are to be determined. Also, the deviation from the ideal bond angle is to be explained.

Concept introduction:

The steps to determine the molecular shape of a given molecule are as follows:

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 10.1 - Write a Lewis structure for H2S; ; SOCl2. Ch. 10.1 - Prob. 10.1BFP Ch. 10.1 - Prob. 10.2AFP Ch. 10.1 - Prob. 10.2BFP Ch. 10.1 - Prob. 10.3AFP Ch. 10.1 - Prob. 10.3BFP Ch. 10.1 - Prob. 10.4AFP Ch. 10.1 - Prob. 10.4BFP Ch. 10.1 - Write a Lewis structure with minimal formal...Ch. 10.1 - Prob. 10.5BFP

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