Chemistry: The Science in Context (Fifth Edition)
5th Edition
ISBN: 9780393615142
Author: Stacey Lowery Bretz, Geoffrey Davies, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: W. W. Norton & Company
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Chapter 10, Problem 10.30QP
Interpretation Introduction
Interpretation: The reason corresponding to the fact that the boiling point of phosphine, 
, is lower than that of ammonia, 
, even though 
has twice the molar mass of 
is to be stated.
Concept introduction: In all the intermolecular interactions hydrogen bonding is strongest interaction. Hydrogen bond is a type of electrostatic attraction present between the hydrogen bound with an electronegative element 
and another electronegative element which have the lone pair of electron.
To determine: The reason corresponding to the fact that the boiling point of phosphine, , is lower than that of ammonia, , even though has twice the molar mass of .
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30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
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diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
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4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
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I2 I 7.46 x 10-
45
kg m²
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O2 I 1.91 x 101
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for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Problem 30 of 20
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Draw the principal organic product of the following reaction.
Chapter 10 Solutions
Chemistry: The Science in Context (Fifth Edition)
Ch. 10.3 - Prob. 1PECh. 10.3 - Prob. 2PECh. 10.5 - Prob. 3PECh. 10.5 - Prob. 4PECh. 10.6 - Prob. 5PECh. 10.7 - Prob. 6PECh. 10.8 - Prob. 7PECh. 10 - Prob. 10.1VPCh. 10 - Prob. 10.2VPCh. 10 - Prob. 10.3VP
Ch. 10 - Prob. 10.4VPCh. 10 - Prob. 10.5VPCh. 10 - Prob. 10.6VPCh. 10 - Prob. 10.7VPCh. 10 - Prob. 10.8VPCh. 10 - Prob. 10.9QPCh. 10 - Prob. 10.10QPCh. 10 - Prob. 10.11QPCh. 10 - Prob. 10.12QPCh. 10 - Prob. 10.13QPCh. 10 - Prob. 10.14QPCh. 10 - Prob. 10.15QPCh. 10 - Prob. 10.16QPCh. 10 - Prob. 10.17QPCh. 10 - Prob. 10.18QPCh. 10 - Prob. 10.19QPCh. 10 - Prob. 10.20QPCh. 10 - Prob. 10.21QPCh. 10 - Prob. 10.22QPCh. 10 - Prob. 10.23QPCh. 10 - Prob. 10.24QPCh. 10 - Prob. 10.25QPCh. 10 - Prob. 10.26QPCh. 10 - Prob. 10.27QPCh. 10 - Prob. 10.28QPCh. 10 - Prob. 10.29QPCh. 10 - Prob. 10.30QPCh. 10 - Prob. 10.31QPCh. 10 - Prob. 10.32QPCh. 10 - Prob. 10.33QPCh. 10 - Prob. 10.34QPCh. 10 - Prob. 10.35QPCh. 10 - Prob. 10.36QPCh. 10 - Prob. 10.37QPCh. 10 - Prob. 10.38QPCh. 10 - Prob. 10.39QPCh. 10 - Prob. 10.40QPCh. 10 - Prob. 10.41QPCh. 10 - Prob. 10.42QPCh. 10 - Prob. 10.43QPCh. 10 - Prob. 10.44QPCh. 10 - Prob. 10.45QPCh. 10 - Prob. 10.46QPCh. 10 - Prob. 10.47QPCh. 10 - Prob. 10.48QPCh. 10 - Prob. 10.49QPCh. 10 - Prob. 10.50QPCh. 10 - Prob. 10.51QPCh. 10 - Prob. 10.52QPCh. 10 - Prob. 10.53QPCh. 10 - Prob. 10.54QPCh. 10 - Prob. 10.55QPCh. 10 - Prob. 10.56QPCh. 10 - Prob. 10.57QPCh. 10 - Prob. 10.58QPCh. 10 - Prob. 10.59QPCh. 10 - Prob. 10.60QPCh. 10 - Prob. 10.61QPCh. 10 - Prob. 10.62QPCh. 10 - Prob. 10.63QPCh. 10 - Prob. 10.64QPCh. 10 - Prob. 10.65QPCh. 10 - Prob. 10.66QPCh. 10 - Prob. 10.67QPCh. 10 - Prob. 10.68QPCh. 10 - Prob. 10.69QPCh. 10 - Prob. 10.70QPCh. 10 - Prob. 10.71QPCh. 10 - Prob. 10.72QPCh. 10 - Prob. 10.73QPCh. 10 - Prob. 10.74QPCh. 10 - Prob. 10.75QPCh. 10 - Prob. 10.76QPCh. 10 - Prob. 10.77QPCh. 10 - Prob. 10.78QPCh. 10 - Prob. 10.79QPCh. 10 - Prob. 10.80QPCh. 10 - Prob. 10.81QPCh. 10 - Prob. 10.82QPCh. 10 - Prob. 10.83QPCh. 10 - Prob. 10.84QPCh. 10 - Prob. 10.85QPCh. 10 - Prob. 10.86QPCh. 10 - Prob. 10.87QPCh. 10 - Prob. 10.88QPCh. 10 - Prob. 10.89QPCh. 10 - Prob. 10.90QPCh. 10 - Prob. 10.91QPCh. 10 - Prob. 10.92QPCh. 10 - Prob. 10.93QPCh. 10 - Prob. 10.94QPCh. 10 - Prob. 10.95QPCh. 10 - Prob. 10.96QPCh. 10 - Prob. 10.97QPCh. 10 - Prob. 10.98QPCh. 10 - Prob. 10.99QPCh. 10 - Prob. 10.100QPCh. 10 - Prob. 10.101QPCh. 10 - Prob. 10.102QPCh. 10 - Prob. 10.103QPCh. 10 - Prob. 10.104QPCh. 10 - Prob. 10.105APCh. 10 - Prob. 10.106APCh. 10 - Prob. 10.107APCh. 10 - Prob. 10.108APCh. 10 - Prob. 10.109APCh. 10 - Prob. 10.111APCh. 10 - Prob. 10.110APCh. 10 - Prob. 10.112APCh. 10 - Prob. 10.113APCh. 10 - Prob. 10.114APCh. 10 - Prob. 10.115APCh. 10 - Prob. 10.116APCh. 10 - Prob. 10.117APCh. 10 - Prob. 10.118APCh. 10 - Prob. 10.119AP
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