Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Question
Chapter 10, Problem 10.15E
(a)
Interpretation Introduction
Interpretation:
The radiation suitable for diagnosis has to be given.
(b)
Interpretation Introduction
Interpretation:
The radiation suitable for therapy has to be given.
(c)
Interpretation Introduction
Interpretation:
The two radioactive nuclides that are used in body imaging have to be given.
(d)
Interpretation Introduction
Interpretation:
The half live of the radioactive nuclides has to be given.
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R₂
R₁
R₁
a
R
Rg
Nu
R₂
Rg
R₁
R
R₁₂
R3
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R
Nu enolate forming
R₁ R
B-Alkylated carbonyl
species or amines
Cyclic B-Ketoester
R₁₁
HOB
R
R₁B
R
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B-Hydroxy carbonyl
R
diester
R2 R3
R₁
RB
OR
R₂ 0
aB-Unsaturated carbonyl
NaOR
Aldol
HOR
reaction
1) LDA
2) R-X
3) H₂O/H₂O
ketone,
aldehyde
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2) acid chloride
3) H₂O'/H₂O
0
O
R₁
R₁
R
R₁
R₁₂
Alkylated a-carbon
R₁
H.C
R₁
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acetoacetic
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B-Ketoester
ester
R₁
HO
R₂ R
B-Dicarbonyl
HO
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malonic ester
Write the reagents required to bring about each reaction next to the arrows shown.
Next, record any regiochemistry or stereochemistry considerations relevant to the
reaction. You should also record any key aspects of the mechanism, such as forma-
tion of an important intermediate, as a helpful reminder. You may want to keep
track of all reactions that make carbon-carbon bonds, because these help you build
large molecules from smaller fragments. This especially applies to the reactions in…
Provide the reasonable steps to achieve the following synthesis.
Identify which compound is more acidic. Justify your choice.
Chapter 10 Solutions
Chemical Principles: The Quest for Insight
Ch. 10 - Prob. 10A.1ASTCh. 10 - Prob. 10A.1BSTCh. 10 - Prob. 10A.2ASTCh. 10 - Prob. 10A.2BSTCh. 10 - Prob. 10A.3ASTCh. 10 - Prob. 10A.3BSTCh. 10 - Prob. 10A.1ECh. 10 - Prob. 10A.2ECh. 10 - Prob. 10A.3ECh. 10 - Prob. 10A.4E
Ch. 10 - Prob. 10A.5ECh. 10 - Prob. 10A.6ECh. 10 - Prob. 10A.7ECh. 10 - Prob. 10A.8ECh. 10 - Prob. 10A.9ECh. 10 - Prob. 10A.10ECh. 10 - Prob. 10A.11ECh. 10 - Prob. 10A.12ECh. 10 - Prob. 10A.13ECh. 10 - Prob. 10A.14ECh. 10 - Prob. 10A.15ECh. 10 - Prob. 10A.16ECh. 10 - Prob. 10A.17ECh. 10 - Prob. 10A.18ECh. 10 - Prob. 10A.19ECh. 10 - Prob. 10A.20ECh. 10 - Prob. 10A.21ECh. 10 - Prob. 10A.22ECh. 10 - Prob. 10A.23ECh. 10 - Prob. 10A.24ECh. 10 - Prob. 10A.25ECh. 10 - Prob. 10A.26ECh. 10 - Prob. 10B.1ASTCh. 10 - Prob. 10B.1BSTCh. 10 - Prob. 10B.2ASTCh. 10 - Prob. 10B.2BSTCh. 10 - Prob. 10B.1ECh. 10 - Prob. 10B.2ECh. 10 - Prob. 10B.3ECh. 10 - Prob. 10B.4ECh. 10 - Prob. 10B.5ECh. 10 - Prob. 10B.6ECh. 10 - Prob. 10B.7ECh. 10 - Prob. 10B.8ECh. 10 - Prob. 10B.9ECh. 10 - Prob. 10B.10ECh. 10 - Prob. 10B.11ECh. 10 - Prob. 10B.12ECh. 10 - Prob. 10B.13ECh. 10 - Prob. 10B.17ECh. 10 - Prob. 10B.18ECh. 10 - Prob. 10B.19ECh. 10 - Prob. 10C.1ASTCh. 10 - Prob. 10C.1BSTCh. 10 - Prob. 10C.2ASTCh. 10 - Prob. 10C.2BSTCh. 10 - Prob. 10C.1ECh. 10 - Prob. 10C.2ECh. 10 - Prob. 10C.3ECh. 10 - Prob. 10C.4ECh. 10 - Prob. 10C.5ECh. 10 - Prob. 10C.6ECh. 10 - Prob. 10C.7ECh. 10 - Prob. 10C.8ECh. 10 - Prob. 10C.9ECh. 10 - Prob. 10C.10ECh. 10 - Prob. 10.1ECh. 10 - Prob. 10.2ECh. 10 - Prob. 10.3ECh. 10 - Prob. 10.4ECh. 10 - Prob. 10.6ECh. 10 - Prob. 10.8ECh. 10 - Prob. 10.9ECh. 10 - Prob. 10.10ECh. 10 - Prob. 10.12ECh. 10 - Prob. 10.15ECh. 10 - Prob. 10.17ECh. 10 - Prob. 10.19ECh. 10 - Prob. 10.20ECh. 10 - Prob. 10.21E
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