(a) Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated. Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

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Answer 1

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of N2 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm ☑ 5 00. 18 Ar

Answer 2

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Answer 3

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Answer 4

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Answer 5

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

Answer 6

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Answer 7

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Answer 8

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 1.1 - While the most common isotope of nitrogen has a...Ch. 1.2 - Label each bond in the following compounds as...Ch. 1.3 - Draw a valid Lewis structure for each species. a....Ch. 1.3 - Prob. 9P Ch. 1.4 - Draw Lewis structures for each molecular formula....Ch. 1.6 - Classify each pair of compounds as isomers or...Ch. 1.6 - Prob. 12P Ch. 1.6 - Prob. 13P Ch. 1.6 - Prob. 14P Ch. 1.6 - Prob. 16P

Solution Summary: The author explains that bond length and bond strength are determined by s character. Resonance plays a significant role in stabilizing the molecule.

Concept explainers

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Chapter 1 Solutions

Solution Summary: The author explains that bond length and bond strength are determined by s character. Resonance plays a significant role in stabilizing the molecule.

Concept explainers

(b) Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated. Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Chapter 1 Solutions

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.