Chemistry: Structures and Properties, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package
1st Edition
ISBN: 9780321974617
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 1, Problem 83E
Use the mass spectrum of lead shown here to estimate the
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CH3
CH
H3C
CH3
H
OH
H3C-
-OCH2CH3
H3C
H
-OCH3
For each of the above compounds, do the following:
1. List the wave numbers of all the IR bands in the 1350-4000 cm-1 region.
For each one, state what bond or group it represents.
2. Label equivalent sets of protons with lower-case letters. Then, for each 1H NMR
signal, give the 8 value, the type of splitting (singlet, doublet etc.), and the number
protons it represents.
of
letter
δ value
splitting
# of protons
3. Redraw the compound and label equivalent sets of carbons with lower-case
letters.
Then for each set of carbons give the 5 value and # of carbons it represents.
letter
δ value
# of carbons
Draw the correct ionic form(s) of arginine at the pKa and PI in your titration curve. Use your titration curve to help you determine which form(s) to draw out.
Chapter 1 Solutions
Chemistry: Structures and Properties, Books a la Carte Plus MasteringChemistry with eText -- Access Card Package
Ch. 1 - Which statement is true about matter? a) Matter is...Ch. 1 - A chemist mixes sodium with water and witnesses a...Ch. 1 - Two samples of a compound containing elements A...Ch. 1 - A compound containing only carbon and hydrogen has...Ch. 1 - Which concept was demostrated by Rutherford’s gold...Ch. 1 - A student re-creates Millikan’s oil drop...Ch. 1 - Prob. 7SAQCh. 1 - An isotope of an element contains 82 protons and...Ch. 1 - How many electrons are in the Cr3+ ion? 24...Ch. 1 - A naturally occurring sample of an element...
Ch. 1 - Copper has an atomic mass of 63.55 amu and two...Ch. 1 - Which sample contains the greatest number of...Ch. 1 - Explain this statement in your own words and give...Ch. 1 - Explain the main goal of chemistry.Ch. 1 - What are two different ways to classify matter?Ch. 1 - How do solids, liquids, and gases differ?Ch. 1 - Explain the difference between a pure substance...Ch. 1 - Explain the difference between an element and a...Ch. 1 - Explain the difference between a homogeneous and a...Ch. 1 - Describe the scientific approach to knowledge. How...Ch. 1 - Prob. 9ECh. 1 - What observations did Antoine Lavoisier make? What...Ch. 1 - What theory did John Dalton formulate?Ch. 1 - What is wrong with the expression, “That is just a...Ch. 1 - Summarize the history of the atomic idea. How was...Ch. 1 - Prob. 14ECh. 1 - State and explain the law of definite proportions.Ch. 1 - State and explain the law of multiple proportions....Ch. 1 - What are the main ideas in Dalton’s atomic theory?...Ch. 1 - How and by whom was the electron discovered? What...Ch. 1 - Explain Millikan’s oil drop experiment and how it...Ch. 1 - Prob. 20ECh. 1 - Describe Rutherford’s gold foil experiment. How...Ch. 1 - Describe Rutherford’s nuclear model of the atom....Ch. 1 - If matter is mostly empty space, as suggested by...Ch. 1 - List the three subatomic particles that compose...Ch. 1 - What defines an element?Ch. 1 - Explain the difference between Z (the atomic...Ch. 1 - Where do elements get their names?Ch. 1 - What are isotopes? What is percent natural...Ch. 1 - Describe the two different notations used to...Ch. 1 - Prob. 30ECh. 1 - Prob. 31ECh. 1 - Explain how a mass spectrometer works. What kind...Ch. 1 - Each shape represents a type of particle (such as...Ch. 1 - Using triangles to represent one type of atom and...Ch. 1 - Classify each substance as a pure substance or a...Ch. 1 - Classify each substance as a pure substance or a...Ch. 1 - Prob. 37ECh. 1 - Complete the table. Substance Pure or mixture Type...Ch. 1 - Determine whether each molecular diagram...Ch. 1 - Determine whether each molecular diagram...Ch. 1 - Classify each statement as an observation, a law,...Ch. 1 - Classify each statement as an observation, a law,...Ch. 1 - A chemist decomposes several samples of carbon...Ch. 1 - When astronomers observe distant galaxies, they...Ch. 1 - Prob. 45ECh. 1 - An automobile gasoline tank holds 21 kg of...Ch. 1 - Two samples of carbon tetrachloride are decomposed...Ch. 1 - Two samples of sodium chloride are decomposed into...Ch. 1 - The mass ratio of sodium to fluorine in sodium...Ch. 1 - Upon decomposition, one sample of magnesium...Ch. 1 - Two different compounds containing osmium and...Ch. 1 - Palladium forms three different compounds with...Ch. 1 - Prob. 53ECh. 1 - Sulfur and fluorine form several different...Ch. 1 - Which statements are consistent with Dalton’s...Ch. 1 - Which statements are inconsistent with Dalton’s...Ch. 1 - Which statements are consistent with Rutherford’s...Ch. 1 - Which statements are inconsistent with...Ch. 1 - A chemist in an imaginary universe, where...Ch. 1 - Imagine a unit of charge called the zorg. A...Ch. 1 - Which statements about subatomic particles are...Ch. 1 - Which statements about subatomic particles are...Ch. 1 - Write isotopic symbols in the form XA (e g., C-13)...Ch. 1 - Write isotopic symbols in the form ZAX for each...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - The amount of carbon-14 in ancient artifacts and...Ch. 1 - Uranium-235 is used in nuclear fission. Determine...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Determine the number of protons and the number of...Ch. 1 - Gallium has two naturally occurring isotopes with...Ch. 1 - Magnesium has three naturally occurring isotopes...Ch. 1 - The atomic mass of fluorine is 18.998 amu, and its...Ch. 1 - The atomic mass of copper is 63.546 amu. Do any...Ch. 1 - An element has two naturally occurring isotopes....Ch. 1 - An element has four naturally occuring isotopes...Ch. 1 - Bromine has two naturally occurring isotopes...Ch. 1 - Silicon has three naturally occurring isotopes...Ch. 1 - Use the mass spectrum of europium shown here to...Ch. 1 - Use the mass spectrum of rubidium shown here to...Ch. 1 - A 7.83-g sample of HCN contains 0.290 g of H and...Ch. 1 - The ratio of sulfur to oxygen by mass in SO2 is...Ch. 1 - Use the mass spectrum of lead shown here to...Ch. 1 - Use the mass spectrum of mercury shown here to...Ch. 1 - Nuclei with the same number of neutrons but...Ch. 1 - Fill in the blanks to complete the table. Symbol z...Ch. 1 - Silver is composed of two naturally occurring...Ch. 1 - To the right is a representation of 50 atoms of a...Ch. 1 - The ratio of oxygen to nitrogen by mass in NO2 is...Ch. 1 - Naturally occurring cobalt consists of only one...Ch. 1 - A 7.36-g sample of copper is contaminated with an...Ch. 1 - The ratio of the mass of O to the mass of N in...Ch. 1 - Naturally occurring magnesium has an atomic mass...Ch. 1 - A volatile liquid (one that readily evaporates) is...Ch. 1 - The diagram to the right represents solid carbon...Ch. 1 - Use triangles to represent atoms of element A and...Ch. 1 - Identify each statement as being most like an...
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