Chapter 1, Problem 80CP

(a)

Interpretation Introduction

Interpretation:

To identify the hybridization state of C_a, C_b and C_c in the given compound.  To determine the bond angle of H-C_a-C_b and C_a-C_b-C_c and to describe the relative orientation of the p orbitals on C_a and C_c

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound.  This mixing of hybrid orbitals is known as hybridization.  The hybridization determines the geometry of the particular atom in the compound.  Shortly to say

$s{p}^{3}hybridized$ =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

$s{p}^{2}hybridized$ =trigonal planar

$sp$ $hybridized$ =linear

To identify: To identify the hybridization state of C_a, C_b and C_c.

(b)

Interpretation Introduction

Interpretation:

To identify the hybridization state of C_a, C_b and C_c in the given compound.  To determine the bond angle of H-C_a-C_b and C_a-C_b-C_c and to describe the relative orientation of the p orbitals on C_a and C_c

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound.  This mixing of hybrid orbitals is known as hybridization.  The hybridization determines the geometry of the particular atom in the compound.  Shortly to say

$s{p}^{3}hybridized$ =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

$s{p}^{2}hybridized$ =trigonal planar

$sp$ $hybridized$ =linear

(c)

Interpretation Introduction

Interpretation:

To identify the hybridization state of C_a, C_b and C_c in the given compound.  To determine the bond angle of H-C_a-C_b and C_a-C_b-C_c and to describe the relative orientation of the p orbitals on C_a and C_c

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound.  This mixing of hybrid orbitals is known as hybridization.  The hybridization determines the geometry of the particular atom in the compound.  Shortly to say

$s{p}^{3}hybridized$ =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

$s{p}^{2}hybridized$ =trigonal planar

$sp$ $hybridized$ =linear

(d)

Interpretation Introduction

Interpretation:

To identify the hybridization state of C_a, C_b and C_c in the given compound.  To determine the bond angle of H-C_a-C_b and C_a-C_b-C_c and to describe the relative orientation of the p orbitals on C_a and C_c

Concept introduction:

The atomic orbitals mix together to form a hybrid orbital which is suitable for forming bonds between the atoms to form a compound.  This mixing of hybrid orbitals is known as hybridization.  The hybridization determines the geometry of the particular atom in the compound.  Shortly to say

$s{p}^{3}hybridized$ =tetrahedral

trigonal pyramidal(if one lone pair of electron is present)

bent geometry (if two lone pair of electrons are present)

$s{p}^{2}hybridized$ =trigonal planar

$sp$ $hybridized$ =linear