CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
7th Edition
ISBN: 9781119497325
Author: JESPERSEN
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Question
Chapter 1, Problem 71RQ
Interpretation Introduction
Interpretation:
The distance in miles between the brightest star Sirius and Earth is to be calculated.
Concept Introduction:
Unit conversion is defined as the process in which multiple steps are used to convert the unit of measurement for the same given quantity. It is determined by multiplying with a conversion factor.
The fraction in which the numerator and denominator both are the same quantities but are determined in different units is known as a conversion factor.
Expert Solution & Answer

Trending nowThis is a popular solution!

Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 1 Solutions
CHEMISTRY:MOLECULAR NATURE (LL)W/ACCESS
Ch. 1 - Practice Exercise 1.1
What is the process of the...Ch. 1 - Practice Exercise 1.2
Classify the following as an...Ch. 1 - Practice Exercise 1.3
Each of the following can be...Ch. 1 - Practice Exercise 1.4
Each of these properties can...Ch. 1 - Prob. 5PECh. 1 - Prob. 6PECh. 1 - What is 355CinF? (Hint: What tool relates these...Ch. 1 - Convert 55F to its Celsius temperature. What...Ch. 1 - Prob. 9PECh. 1 - Perform the following calculations involving...
Ch. 1 - Practice Exercise 1.11
Use dimensional analysis to...Ch. 1 - Use dimensional analysis to perform the following...Ch. 1 - A 15.0 mL sample of polystyrene used in insulated...Ch. 1 - Practice Exercise 1.14
A crystal of salt was grown...Ch. 1 - A gold-colored metal object has a mass of 365 g...Ch. 1 - Practice Exercise 1.16
A certain metal alloy has a...Ch. 1 - Practice Exercise 1.17
Table wines have a minimum...Ch. 1 - Practice Exercise 1.18
Diabetes can cause a...Ch. 1 - After some thought, give two reasons why a course...Ch. 1 - What steps are involved in the scientific method?Ch. 1 - Prob. 3RQCh. 1 - Can a theory be proved to be correct? Can a theory...Ch. 1 - 1.5 Define matter. Which are examples of matter?...Ch. 1 - Define (a) element, (b) compound, (c) mixture, (d)...Ch. 1 - 1.7 Which kind of change, chemical or physical, is...Ch. 1 - Prob. 8RQCh. 1 - 1.9 What is the name of each of the following...Ch. 1 - For each of the following molecular pictures,...Ch. 1 - 1.11 Consider the following four samples of...Ch. 1 - 1.12 What is a physical change? What is a chemical...Ch. 1 - 1.13 “A sample of calcium (an electrically...Ch. 1 - 1.14 In places like Saudi Arabia, freshwater is...Ch. 1 - How does a chemical property differ from a...Ch. 1 - Distinguish between an extensive and an intensive...Ch. 1 - Determine whether each of the following is an...Ch. 1 - Describe one or more physical properties of each...Ch. 1 - Why must measurements always be written with a...Ch. 1 - What is the only SI base unit that includes a...Ch. 1 - Which SI units are mainly used in chemistry?Ch. 1 - What are derived units? Give two examples of...Ch. 1 - What is the meaning of each of the following...Ch. 1 - What reference points do we use in calibrating the...Ch. 1 - In each pair, which is larger: (a) A Fahrenheit...Ch. 1 - 1.26 Define the term significant figures.
Ch. 1 - Explain how to round numbers.Ch. 1 - What is the difference between accuracy and...Ch. 1 - 1.29 Suppose a length had been reported to be...Ch. 1 - What is the difference between the treatment of...Ch. 1 - When constructing a conversion factor between two...Ch. 1 - Suppose someone suggested using the fraction 3...Ch. 1 - In 1 hour there are 3600 seconds. By what...Ch. 1 - If you were to convert the measured length 4.165...Ch. 1 - 1.35 Write the equation that defines density....Ch. 1 - Compare density and specific gravity. What is the...Ch. 1 - 1.37 Give four sets of units for density. What...Ch. 1 - 1.38 Silver has a density of . Express this as an...Ch. 1 - Determine whether each of the following is a...Ch. 1 - 1.40 Determine whether each of the following is a...Ch. 1 - At room temperature, what is the state of each of...Ch. 1 - At room temperature, determine the appropriate...Ch. 1 - What number should replace the question mark in...Ch. 1 - 1.44 What numbers should replace the question...Ch. 1 - Perform the following conversions. (a) 57CtoF (b)...Ch. 1 - Perform the following conversions. (a) 98FtoC (b)...Ch. 1 - The temperature of the core of the sun is...Ch. 1 - Natural gas is mostly methane, a substance that...Ch. 1 - A healthy dog has a temperature ranging from...Ch. 1 - Prob. 50RQCh. 1 - The length of a wire was measured using two...Ch. 1 - What are the temperatures being measured in the...Ch. 1 - 1.53 How many significant figures do the following...Ch. 1 - How many significant figures do the following...Ch. 1 - 1.55 Perform the following arithmetic and round...Ch. 1 - 1.56 Perform the following arithmetic and round...Ch. 1 - Which are exact numbers and which ones have a...Ch. 1 - Prob. 58RQCh. 1 - 1.59 Perform the following conversions.
Ch. 1 - 1.60 Perform the following conversions.
Ch. 1 - 1.61 Perform the following conversions. If...Ch. 1 - 1.62 Perform the following conversions. If...Ch. 1 - 1.63 Perform the following conversions....Ch. 1 - Prob. 64RQCh. 1 - The human stomach can expand to hold up to 4.2...Ch. 1 - In the movie Cool Hand Luke (1967), Luke wagers...Ch. 1 - 1.67 The winds in a hurricane can reach almost 200...Ch. 1 - 1.68 A bullet is fired at a speed of 2435 ft/s....Ch. 1 - 1.69 A bullet leaving the muzzle of a pistol was...Ch. 1 - 1.70 On average, water flows over Niagara Falls at...Ch. 1 - Prob. 71RQCh. 1 - *1.72 One degree of latitude on the earth’s...Ch. 1 - Calculate the density of kerosene, in g/mL, if its...Ch. 1 - Calculate the density of magnesium, in g/cm3, if...Ch. 1 - Acetone, the solvent in some nail polish removers,...Ch. 1 - A glass apparatus contains 26.223 g of water when...Ch. 1 - 1.77 Chloroform, a chemical once used as an...Ch. 1 - Gasolines density is about 0.65 g/mL. How much...Ch. 1 - Prob. 79RQCh. 1 - Prob. 80RQCh. 1 - The space shuttle uses liquid hydrogen as its...Ch. 1 - Prob. 82RQCh. 1 - 1.83 Some time ago, a U.S. citizen traveling in...Ch. 1 - Driving to work one day, one of the authors of...Ch. 1 - Prob. 85RQCh. 1 - Prob. 86RQCh. 1 - Prob. 87RQCh. 1 - A pycnometer is a glass apparatus used for...Ch. 1 - 1.89 Radio waves travel at the speed of light, ....Ch. 1 - Prob. 90RQCh. 1 - Prob. 91RQCh. 1 - Aerogel or solid smoke" is a novel material that...Ch. 1 - A liquid known to be either ethanol (ethyl...Ch. 1 - An unknown liquid was found to have a density of...Ch. 1 - 1.95 There exists a single temperature at which...Ch. 1 - In the text, the Kelvin scale of temperature is...Ch. 1 - Density measurements can be used to analyze...Ch. 1 - An artist's statue has a surface area of 14.6ft2....Ch. 1 - What is the volume in cubic millimeters of a 3.54...Ch. 1 - 1.100 A solution is defined as a uniform mixture...Ch. 1 - How do you know that Coca-Cola is not a compound?...Ch. 1 - Find two or more web sites that give the values...Ch. 1 - 1.103 Reference books such as the Handbook of...Ch. 1 - A student used a 250 mL graduated cylinder having...Ch. 1 - Prob. 105RQCh. 1 - Gold has a density of 19.31gcm-3. How many grams...Ch. 1 - A Boeing 747 jet airliner carrying 568 people...Ch. 1 - *1.108 Download a table of data for the density of...Ch. 1 - List the physical and chemical properties...Ch. 1 - Prob. 110RQ
Knowledge Booster
Similar questions
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forward
- Explain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forwardProtecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forward
- Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forwardShow the mechanism steps to obtain the lowerenergy intermediate: *see imagearrow_forwardSoap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning


General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning

Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning