(a) Interpretation: The boiling point of water in o M (new temperature scale) needs to be calculated if the melting point of mercury is 0 o M or − 38.9 o C and boiling point of mercury is 100 o M or 356.9 o C. Concept introduction: The conversion factor required to determine the results in different or desired scale by equivalizing different units. The temperature of the sample at given scale degree M can be identified as follows: ( T calculated ( in o M ) – T lower ( in o M ) ) ( T higher ( in o M ) – T lower ( in o M ) ) = ( T calculated ( in o C ) – T lower ( in o C ) ) ( T higher ( in o C ) – T lower ( in o C ) )
(a) Interpretation: The boiling point of water in o M (new temperature scale) needs to be calculated if the melting point of mercury is 0 o M or − 38.9 o C and boiling point of mercury is 100 o M or 356.9 o C. Concept introduction: The conversion factor required to determine the results in different or desired scale by equivalizing different units. The temperature of the sample at given scale degree M can be identified as follows: ( T calculated ( in o M ) – T lower ( in o M ) ) ( T higher ( in o M ) – T lower ( in o M ) ) = ( T calculated ( in o C ) – T lower ( in o C ) ) ( T higher ( in o C ) – T lower ( in o C ) )
The boiling point of water in oM (new temperature scale) needs to be calculated if the melting point of mercury is 0 oM or − 38.9 oC and boiling point of mercury is 100 oM or 356.9 oC.
Concept introduction:
The conversion factor required to determine the results in different or desired scale by equivalizing different units.
The temperature of the sample at given scale degree M can be identified as follows:
(Tcalculated(in oM)– Tlower(in oM))(Thigher( in oM)– Tlower(in oM)) = (Tcalculated( in oC)– Tlower(in oC))(Thigher(in oC)– Tlower( in oC))
Interpretation Introduction
(b)
Interpretation:
The absolute zero temperature in o M needs to be determined if melting point of mercury is 0 o M or − 38.9 o C and boiling point of mercury is 100 o M and 356.9 o C.
Concept introduction:
The conversion factor required to determine the results in different or desired scale by equivalizing different units.
The temperature of the sample at given scale degree M can be identified as follows:
(Tcalculated(in oM)– Tlower(in oM))(Thigher( in oM)– Tlower(in oM)) = (Tcalculated( in oC)– Tlower(in oC))(Thigher(in oC)– Tlower( in oC))
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
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Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.