A chemist in a galaxy far, far away performed the Millikan oil drop experiment and got the following resultsfor the charges on various drops. Use these data to calculate the charge of the electron in zirkombs.1.21 x 10-12zirkombs3.62 x 10 -12zirkombs7.84 x 10712zirkombs6.03 x 10-13zirkombsCharge =zirkombs, or an integer fraction of this charge

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Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter1: The Nature Of Chemistry

Section1.13: The Periodic Table

Problem 1.9E

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There are 1.699 1022 atoms in 1.000 g of chlorine. Assume that chlorine atoms are spheres of radius 0.99 and that they are lined up side by side in a 0.5-g sample. How many miles in length is the line of chlorine atoms in the sample?
In 1886 Eugene Goldstein observed positively charged particles moving in the opposite direction to electrons in a cathode ray tube (illustrated below). From their mass, he concluded that these particles were formed from residual gas in the tube. For example, if the cathode ray tube contained helium, the canal rays consisted of He+ ions. Describe a process that could lead to these ions. Canal rays. In 1886, Eugene Goldstein detected a stream of particles traveling in the direction opposite to that of the negatively charged cathode rays (electrons). He called this stream of positive particles "canal rays:"
Chlorine has two isotopes, Cl-35 and Cl-37. Their abundances are 75.53% and 24.47%, respectively. Assume that the only hydrogen isotope present is H-1. (a) How many different HCI molecules are possible? (b) What is the sum of the mass numbers of the two atoms in each molecule? (c) Sketch the mass spectrum for HCI if all the positive ions are obtained by removing a single electron from an HCI molecule.
Calculate the atomic mass of each of the following elements using the given data for the percentage abundance and mass of each isotope. a. Silver: 51.82% 107Ag (106.9 amu) and 48.18% 109Ag (108.9 amu) b. Silicon: 92.21% 28Si (27.98 amu), 4.70% 29Si (28.98 amu), and 3.09% 30Si (29.97 amu)
2.92 A candy manufacturer makes chocolate-covered cherries. Although all of the products look roughly the same, 3% of them are missing the cherry. The mass of the candy with a cherry is 18.5 g; those missing the cherry weigh only 6.4 g. (a) How would you compute the average mass of a box of 100 of these chocolate covered cherries from this manufacturer? (b) I low is this question analogous to the determination of atomic weights?
The early alchemists used to do an experiment in which water was boiled for several days in a sealed glass container. Eventually. some solid residue would appear in die bottom of the flask, which was interpreted to mean that some of the water in the flask had been converted into earth. When Lavoisier repeated this experiment, he found that the water weighed the same before and after heating, and the mass of die flask plus the solid residue equaled the original mass of the flask. Were the alchemists correct? Explain what really happened. (This experiment is described in the article by A. F. Scott in Scientific American, January 1984.)
Mass spectrometric analysis showed that there are four isotopes of an unknown element having the following masses and abundances: Three elements in the periodic table that have atomic weights near these values are lanthanum (La), atomic number 57, atomic weight 138.9055; cerium (Ce), atomic number 58, atomic weight 140.115; and praseodymium (Pr), atomic number 59, atomic weight 140.9076. Using the data above, calculate the atomic weight, and identify the element if possible.
There are 2.619 1022 atoms in 1.000 g of sodium. Assume that sodium atoms are spheres of radius 1.86 and that they are lined up side by side. How many miles in length is the line of sodium atoms?
The element europium exists in nature as two isotopes: 151Eu has a mass of 150.9196 u and 153Eu has a mass of 152.9209 u. The average atomic mass of europium is 151.96 u. Calculate the relative abundance of the two europium isotopes.
Two elements, R and Q, combine to form two binary compounds. In the first compound, 14.0 g of R combines with 3.00 g of Q. In the second compound, 7.00 g of R combines with 4.50 g of Q. Show that these data are in accord with the law of multiple proportions. If the formula of the second compound is RQ, what is the formula of the first compound?
Early tables of atomic weights (masses) were generated by measuring the mass of a substance that reacts with 1.00 g of oxygen. Given the following data and taking the atomic mass of hydrogen as 1.00, generate a table of relative atomic masses for oxygen, sodium, and magnesium. Element Mass That Combines with 1.00g Oxygen Assumed Formula Hydrogen 0.126 g HO Sodium 2.875 g NaO Magnesium 1.500 g MgO How do your values compare with those in the periodic table? How do you account for any differences?
These questions concern the work of J. J. Thomson: From Thomson’s work, which particles do you think he would feel are most important in the formation of compounds (chemical changes) and why? Of the remaining two subatomic particles, which do you place second in importance for forming compounds and why? Come up with three models that explain Thomson’s findings and evaluate them. To be complete you should include Thomson’s findings.

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