EBK PUSHING ELECTRONS
EBK PUSHING ELECTRONS
4th Edition
ISBN: 9781285633237
Author: Weeks
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 1, Problem 38EQ

Nitrobenzene has the skeleton

Chapter 1, Problem 38EQ, Nitrobenzene has the skeleton



The number of available valence electrons is: from the phenyl , example  1

The number of available valence electrons is: from the phenyl group, ____; from the nitrogen atom, ____; and from each of two oxygen atoms, ____, for a total of ____. Filling in all single bonds and adding the appropriate unshared pairs gives

______________________________

The functional group of this structure contains ____ electrons. Therefore, unshared pairs are removed from the nitrogen atom and one of the oxygen atoms; a double bond is added giving

______________________________

which has the correct number of electrons. In this structure the nitrogen atom is sharing ____ pairs of electrons. From each shared pair the nitrogen owns ____ electron for a total of ____. Nitrogen is a Group ____ element and would have outer shell electrons in the unbonded, neutral state. Since the nitrogen atom in nitrobenzene has one fewer electron than it would in the neutral state, it has a formal charge of +1 . This is added to the Lewis structure as + giving

Chapter 1, Problem 38EQ, Nitrobenzene has the skeleton



The number of available valence electrons is: from the phenyl , example  2

Since an electron is negatively charged, a shortage of one electron results in a single positive charge ( + ) on an atom. Conversely, an excess of one electron results in a single negative charge ( 2 ) on an atom. When an atom in a Lewis structure “owns” two fewer electrons than it would have in the neutral, unbonded state, it is denoted by ++ or +2 and, conversely, = or – 2.

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Chapter 1 Solutions

EBK PUSHING ELECTRONS

Ch. 1 - Prob. 11EQCh. 1 - Adding electrons to the skeleton by making single...Ch. 1 - This is done by removing an unshared pair from...Ch. 1 - Prob. 14EQCh. 1 - Prob. 15EQCh. 1 - Prob. 16EQCh. 1 - The skeleton of acetyl chloride is . Write the...Ch. 1 - Three constitutional isomers exist for the formula...Ch. 1 - A number of constitutional isomers exist for the...Ch. 1 - Using the method outlined above, derive the...Ch. 1 - Prob. 21EQCh. 1 - Prob. 22EQCh. 1 - Prob. 23EQCh. 1 - Prob. 24EQCh. 1 - The skeleton of benzyldimethylamine is The...Ch. 1 - The skeleton is benzaldoxime is The number of...Ch. 1 - Prob. 27EQCh. 1 - Derive Lewis structures for the compounds below....Ch. 1 - Prob. 29EQCh. 1 - Derive Lewis structures for the compounds below....Ch. 1 - Prob. 31EQCh. 1 - Derive Lewis structures for the compounds below....Ch. 1 - The Lewis structure of acetone is Circling the...Ch. 1 - Chloromethane has the Lewis...Ch. 1 - In the Lewis structure for chloromethane, the...Ch. 1 - Prob. 36EQCh. 1 - The oxygen atom in acetone possesses ____ unshared...Ch. 1 - Nitrobenzene has the skeleton The number of...Ch. 1 - Prob. 39EQCh. 1 - Compute and add on the formal charges I these...Ch. 1 - Prob. 41EQCh. 1 - Prob. 42EQCh. 1 - Prob. 43EQCh. 1 - Prob. 44EQCh. 1 - Prob. 45EQCh. 1 - Prob. 46EQCh. 1 - Prob. 47EQCh. 1 - Compute and add on the formal charges in these...Ch. 1 - Prob. 49EQCh. 1 - Prob. 50EQCh. 1 - The n-propyl cation can be formed from a molecule...Ch. 1 - Prob. 52EQCh. 1 - Prob. 53EQCh. 1 - Methanol, CH3OH, is a compound in which the formal...Ch. 1 - When a proton becomes bonded to diethyl ether, by...Ch. 1 - Tetrahydrofuran has the structure When a proton...Ch. 1 - Prob. 57EQCh. 1 - Prob. 58EQCh. 1 - The structure of pyridine is When a proton...Ch. 1 - The carbon atom owns one electron from each of ...Ch. 1 - The n-butyl anion can be formed from When the CLi...Ch. 1 - The isobutyl anion can be formed from When the CNa...Ch. 1 - Prob. 63EQCh. 1 - Ethanol, , is a compound in which the formal...Ch. 1 - The loss of a proton attached to the oxygen atom...Ch. 1 - A very strong base can remove a proton from...Ch. 1 - Prob. 67EQCh. 1 - Prob. 68EQCh. 1 - Prob. 69EQCh. 1 - The homolysis of the OO bond in diacetyl peroxide...Ch. 1 - Prob. 71EQCh. 1 - Prob. 72EQCh. 1 - Prob. 73EQCh. 1 - Prob. 74EQCh. 1 - Prob. 75EQCh. 1 - Heterolytic cleavage of the CO bond to yield a...Ch. 1 - Prob. 77EQCh. 1 - Prob. 78EQCh. 1 - Prob. 79EQCh. 1 - Prob. 80EQ
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