a. After the label fell off a bottle containing a clear liquid believed to be benzene, a chemist measured the density of the liquid to verify its identity. A 25.0-mL portion of the liquid had a mass of 21.95 g. A chemistry handbook lists the density of benzene at15 -C as 0.8787 g/ml. Is the calculated density in agreement with the tabulated value? b An experiment requires 15 0 g of cyclohexane. whose density at 25 °C is 0.7781 g/ml. What volume of cyclohexane should be used? c. A spherical ball of lead has a diameter of 5.0 cm. What is the mass of the sphere if lead has a density of 11.34 g/cm 3 ? (The volume of a sphere is (4 /3) r 3 , where r is the radius.)
a. After the label fell off a bottle containing a clear liquid believed to be benzene, a chemist measured the density of the liquid to verify its identity. A 25.0-mL portion of the liquid had a mass of 21.95 g. A chemistry handbook lists the density of benzene at15 -C as 0.8787 g/ml. Is the calculated density in agreement with the tabulated value? b An experiment requires 15 0 g of cyclohexane. whose density at 25 °C is 0.7781 g/ml. What volume of cyclohexane should be used? c. A spherical ball of lead has a diameter of 5.0 cm. What is the mass of the sphere if lead has a density of 11.34 g/cm 3 ? (The volume of a sphere is (4 /3) r 3 , where r is the radius.)
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, John H. Nelson, Kenneth C. Kemp
a. After the label fell off a bottle containing a clear liquid believed to be benzene, a chemist measured the density of the liquid to verify its identity. A 25.0-mL portion of the liquid had a mass of 21.95 g. A chemistry handbook lists the density of benzene at15 -C as 0.8787 g/ml. Is the calculated density in agreement with the tabulated value? b An experiment requires 15 0 g of cyclohexane. whose density at 25 °C is 0.7781 g/ml. What volume of cyclohexane should be used? c. A spherical ball of lead has a diameter of 5.0 cm. What is the mass of the sphere if lead has a density of 11.34 g/cm3? (The volume of a sphere is (4 /3) r3, where r is the radius.)
The table includes macrostates characterized by 4 energy levels (&) that are
equally spaced but with different degrees of occupation.
a) Calculate the energy of all the macrostates (in joules). See if they all have
the same energy and number of particles.
b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
Don't used Ai solution
In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
b) Calculate the viscosity at 30°C.
T/°C
0
20
40
60
80
η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 1 Solutions
Laboratory Experiments for Chemistry: The Central Science (14th Edition)
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