Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 1, Problem 34E
Is one liter about an ounce, a pint, a quart, or a gallon?
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Don't used hand raiting
It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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ΜΕ ΑΣΦ
Np, N₁ = 82,126
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protons, neutrons
Chapter 1 Solutions
Chemistry (OER)
Ch. 1 - Explain how you could experimentally determine...Ch. 1 - Identify each of the following statements as being...Ch. 1 - Identify each of the following statements as being...Ch. 1 - Identify each of the underlined items as a part of...Ch. 1 - Identify each of the underlined items as a part of...Ch. 1 - According to one theory, the pressure of a gas...Ch. 1 - The amount of heat required to melt 2 lbs of ice...Ch. 1 - Why do we use an objects mass, rather than its...Ch. 1 - What properties distinguish solids from liquids?...Ch. 1 - How does a heterogeneous mixture differ from a...
Ch. 1 - How does a homogeneous mixture differ from a pure...Ch. 1 - How does an element differ from a compound? How...Ch. 1 - How do molecules of elements and molecules of...Ch. 1 - How does an atom differ from a molecule? In what...Ch. 1 - Many of the items you purchase are mixtures of...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - A sulfur atom and a sulfur molecule are not...Ch. 1 - How are the molecules in oxygen gas, the molecules...Ch. 1 - We refer to astronauts in space as weightless, but...Ch. 1 - As we drive an automobile, we don’t think about...Ch. 1 - Matter is everywhere around us. Make a list by...Ch. 1 - When elemental iron corrodes it combines with...Ch. 1 - As stated in the text, convincing examples that...Ch. 1 - Yeast converts glucose to ethanol and carbon...Ch. 1 - Classify the six underlined properties in the...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - The volume of a sample of oxygen gas changed from...Ch. 1 - A 2.0-mer volume of hydrogen gas combined with 1.0...Ch. 1 - Explain the difference between extensive...Ch. 1 - Identify the following properties as either...Ch. 1 - The density (d) of a substance is an intensive...Ch. 1 - Is one liter about an ounce, a pint, a quart, or a...Ch. 1 - Is a meter about an inch, a foot, a yard, or a...Ch. 1 - Indicate the SI base units or derived units that...Ch. 1 - Indicate the SI base units or derived units that...Ch. 1 - Give the name and symbol of the prefixes used with...Ch. 1 - Give the name of the prefix and the quantity...Ch. 1 - A large piece of jewelry has a mass of 132.6 g. A...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Visit this PhET density simulation...Ch. 1 - Express each of the following numbers in...Ch. 1 - Express each of the following numbers in...Ch. 1 - Indicate whether each of the following can be...Ch. 1 - Indicate whether each of the following can be...Ch. 1 - How many significant figures are contained in each...Ch. 1 - How many significant figures are contained in each...Ch. 1 - The following quantities were reported on the...Ch. 1 - Round off each of the following numbers to two...Ch. 1 - Round off each of the following numbers to two...Ch. 1 - Perform the following calculations and report each...Ch. 1 - Perform the following calculations and report each...Ch. 1 - Consider the results of the archery contest shown...Ch. 1 - Classify the following sets of measurements as...Ch. 1 - Write conversion factors (as ratios) for the...Ch. 1 - Write conversion factors (as ratios) for the...Ch. 1 - The label on a soft drink boule gives the volume...Ch. 1 - The label on a box of cereal gives the mass of...Ch. 1 - Soccer is played with a round ball having a...Ch. 1 - A woman’s basketball has a circumference between...Ch. 1 - How many milliliters of a soft drink are contained...Ch. 1 - A barrel of oil is exactly 42 gal. How many liters...Ch. 1 - The diameter of a red blood cell is about 3104 in....Ch. 1 - The distance between the centers of the two oxygen...Ch. 1 - Is a 197-lb weight lifter light enough to compete...Ch. 1 - A very good 197-Ib weight lifter lifted 192 kg in...Ch. 1 - Many medical laboratory tests are run using 5.0 L...Ch. 1 - If an aspirin tablet Contains 325 mg aspirin, how...Ch. 1 - Use scientific (exponential) notation to express...Ch. 1 - Complete the following conversions between SI...Ch. 1 - Gasoline is sold by the liter in many countries....Ch. 1 - Milk is sold by the liter in many Countries. What...Ch. 1 - A long ton is defined as exactly 2240 lb. What is...Ch. 1 - Make the conversion indicated in each of the...Ch. 1 - Make the conversion indicated in each of the...Ch. 1 - Many chemistry conferences have held a 50-Trillion...Ch. 1 - Many chemistry conferences have held a 50-Trillion...Ch. 1 - The gas tank of a certain luxury automobile holds...Ch. 1 - As an instructor is preparing for an experiment,...Ch. 1 - To prepare for a laboratory period, a student lab...Ch. 1 - A chemistry student is 159 cm tall and weighs 45.8...Ch. 1 - In a recent Grand Prix, the winner completed the...Ch. 1 - Solve these problems about lumber dimensions. To...Ch. 1 - The mercury content of a stream was believed to be...Ch. 1 - Calculate the density of aluminum if 27.6 cm3 has...Ch. 1 - Osmium is one of the densest elements known. What...Ch. 1 - Calculate these masses. What is the mass of 6.00...Ch. 1 - Calculate these masses. What is the mass of 4.00...Ch. 1 - Calculate these volumes. What is the volume of 25...Ch. 1 - Calculate these volumes. What is the volume of...Ch. 1 - Convert the boiling temperature of gold, 2966 C,...Ch. 1 - Convert the temperature of scalding water, 54 C,...Ch. 1 - Convert the temperature of the coldest area in a...Ch. 1 - Convert the temperature of dry ice, 77 C, into...Ch. 1 - Convert the boiling temperature of liquid ammonia....Ch. 1 - The label on a pressurized can of spray...Ch. 1 - The weather in Europe was unusually warm during...
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- Please draw the inverted chair forms of the products for the two equilibrium reactions shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No requirement to show or do calculations.] CH3 CH3 HH CH3 1 -CH3arrow_forward5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forward
- The mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward32S 16 Enter your answers numerically separated by a comma. Np. Nn = 跖 ΟΙ ΑΣΦ Submit Request Answer ? protons, neutronsarrow_forward2. Which dimethylcyclohexane compounds shown below exhibit symmetry and therefore are not chiral and would not rotate plane polarized light. 1 CH3 CH CH3 CH3 2 3 CH3arrow_forward
- Can you please explain why the correct answer for this question is letter B? I chose letter A because I thought that a kinetic product was a 1,2-addition. Please give a detailed explanation.arrow_forwardCan you please explain why the answer is structures 2 and 3? Please include a detailed explanation and show how the synthesis can be done with those two structures.arrow_forwardCan you please explain why the correct answer to this question is option 2? I am having trouble understanding how and why. Please provide a detailed explanation and a drawing of how the diene and dienophile would create the product in the question.arrow_forward
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