OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI
8th Edition
ISBN: 9781305271579
Author: Butler
Publisher: IACCENGAGE
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Textbook Question
Chapter 1, Problem 32P
Arrange the following in order of increasing mass:
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Don't used hand raiting
Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 1 Solutions
OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI
Ch. 1 - Classify the following materials as substances or...Ch. 1 - Classify the following materials as substances or...Ch. 1 - A 17th-century chemist wrote of the “simple bodies...Ch. 1 - Since 1800, almost 200 sincere but erroneous...Ch. 1 - A sample of ascorbic acid (vitamin C) is...Ch. 1 - A sample of a compound synthesized and purified in...Ch. 1 - Nitrogen (N) and silicon (Si) form two binary...Ch. 1 - Iodine (I) and fluorine (F) form a series of...Ch. 1 - Vanadium (V) and oxygen (O) form a series of...Ch. 1 - Prob. 10P
Ch. 1 - Prob. 11PCh. 1 - Prob. 12PCh. 1 - Pure nitrogen dioxide (NO2) forms when dinitrogen...Ch. 1 - Gaseous methanol (CH3OH) reacts with oxygen (O2)...Ch. 1 - In J. J. Thompson’s experiment depicted in Figures...Ch. 1 - In the problem 15 above, what is vy , the...Ch. 1 - The natural abundances and isotopic masses of the...Ch. 1 - The natural abundances and isotopic masses of the...Ch. 1 - Prob. 19PCh. 1 - More than half of all the atoms in naturally...Ch. 1 - The isotope of plutonium used for nuclear fission...Ch. 1 - The last “missing” element from the first six...Ch. 1 - Prob. 23PCh. 1 - In 1982, the production of a single atom of...Ch. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Compute the relative molecular masses of the...Ch. 1 - Prob. 28PCh. 1 - Suppose that a person counts out gold atoms at the...Ch. 1 - A gold atom has a diameter of 2.881010m . Suppose...Ch. 1 - The vitamin A molecule has the formula C20H30O ,...Ch. 1 - Arrange the following in order of increasing mass:...Ch. 1 - Mercury is traded by the “flask,” a unit that has...Ch. 1 - Gold costs $400 per troy ounce, and...Ch. 1 - Aluminum oxide (Al2O3) occurs in nature as a...Ch. 1 - Prob. 36PCh. 1 - Soft wood chips weighing 17.2 kg are placed in an...Ch. 1 - In a reproduction of the Millikan oil-drop...Ch. 1 - A rough estimate of the radius of a nucleus is...Ch. 1 - In a neutron star, gravity causes the electrons to...Ch. 1 - Prob. 41APCh. 1 - Naturally occurring rubidium (Rb) consists of two...Ch. 1 - A sample of a gaseous binary compound of boron and...
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