Chapter 1, Problem 1C.14P

Interpretation Introduction

Interpretation: The relation between $B,C$ and $B\text{'},C\text{'}$ has to be stated.

Concept introduction: The van der Waals equation defines the behavior of real gases.  This includes the forces of attraction and repulsion in the real gases.  This is represented by the formula given below as,

  $p=\frac{nRT}{V-nb}-a{\left(\frac{n}{V}\right)}^2$

The Virial equation of state is given by the formula as,

    $p{V}_{\text{m}}=RT\left(1+\frac{B}{V_{\text{m}}}+\frac{C}{V_{\text{m}}^2}+\mathrm{...}\right)$