
(a)
Interpretation:
Whether the statement “
Concept introduction:
An exact number is a completely certain number, that is, which can be counted. For example, 1 kilometer has exactly 1000 meter or 1 dozen has 12 number of items, which is also an exact number.
Exact numbers have infinite significant figures and zero error or uncertainty. Example 12 has infinite significant figures but 12.00 has 4 significant figures. To exactly determine the uncertainty in the final answer of measurement, significant figures are calculated.
The rules for counting significant figures will be as follows:
- Numbers that are non-zero are significant figures.
- The zeros preceding numbers that are non-zero are non-significant as they only define the place of decimal.
- The zeros in between numbers that are non-zero are also significant.
- The zeros after numbers that are non-zero are significant only if the decimal is present in the number.
(b)
Interpretation:
Whether the statement “
Concept introduction:
An exact number is a completely certain number, that is, which can be counted. For example, 1 kilometer has exactly 1000 meter or 1 dozen has 12 number of items, which is also an exact number.
Exact numbers have infinite significant figures and zero error or uncertainty. Example 12 has infinite significant figures but 12.00 has 4 significant figures. To exactly determine the uncertainty in the final answer of measurement, significant figures are calculated.
The rules for counting significant figures will be as follows:
- Numbers that are non-zero are significant figures.
- The zeros preceding numbers that are non-zero are non-significant as they only define the place of decimal.
- The zeros in between numbers that are non-zero are also significant.
- The zeros after numbers that are non-zero are significant only if the decimal is present in the number.
(c)
Interpretation:
Whether the statement that “Mount Everest has
Concept introduction:
An exact number is a completely certain number, that is, which can be counted. For example, 1 kilometer has exactly 1000 meter or 1 dozen has 12 number of items, which is also an exact number.
Exact numbers have infinite significant figures and zero error or uncertainty. Example 12 has infinite significant figures but 12.00 has 4 significant figures. To exactly determine the uncertainty in the final answer of measurement, significant figures are calculated.
The rules for counting significant figures will be as follows:
- Numbers that are non-zero are significant figures.
- The zeros preceding numbers that are non-zero are non-significant as they only define the place of decimal.
- The zeros in between numbers that are non-zero are also significant.
- The zeros after numbers that are non-zero are significant only if the decimal is present in the number.
d)
Interpretation:
Whether the statement that “the world record for
Concept introduction:
An exact number is a completely certain number, that is, which can be counted. For example, 1 kilometer has exactly 1000 meter or 1 dozen has 12 number of items, which is also an exact number.
Exact numbers have infinite significant figures and zero error or uncertainty. Example 12 has infinite significant figures but 12.00 has 4 significant figures. To exactly determine the uncertainty in the final answer of measurement, significant figures are calculated.
The rules for counting significant figures will be as follows:
- Numbers that are non-zero are significant figures.
- The zeros preceding numbers that are non-zero are non-significant as they only define the place of decimal.
- The zeros in between numbers that are non-zero are also significant.
- The zeros after numbers that are non-zero are significant only if the decimal is present in the number.

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Chapter 1 Solutions
CHEMISTRY-MOD.MASTERING (18W)
- TRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forwardRelative Transmittance 0.995 0.99 0.985 0.98 Please draw the structure that is consistent with all the spectral data below in the box and alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows. INFRARED SPECTRUM 1 0.975 3000 2000 Wavenumber (cm-1) 1000 Structure with assigned H peaks 1 3 180 160 140 120 100 f1 (ppm) 80 60 40 20 0 C-13 NMR note that there are 4 peaks between 120-140ppm Integral values equal the number of equivalent protons 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 fl (ppm)arrow_forwardCalculate the pH of 0.0025 M phenol.arrow_forward
- In the following reaction, the OH- acts as which of these? NO2-(aq) + H2O(l) ⇌ OH-(aq) + HNO2(aq)arrow_forwardUsing spectra attached, can the unknown be predicted? Draw the predicition. Please explain and provide steps. Molecular focrmula:C16H13ClOarrow_forwardCalculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10arrow_forward
- The Ka for sodium dihydrogen phosphate is 6.32 x 10-8. Find the pH of a buffer made from 0.15 M H2PO4- and 0.25 M HPO42- .arrow_forwardThe Ka for lactic acid is 1.4 x 10-4. Find the pH of a buffer made from 0.066 M lactic acid and 0.088 M sodium lactate.arrow_forwardZaitsev's Rule 3) (a) Rank the following alkenes in order of decreasing stability. most stable A B C D > > > (b) Rank the following carbocations in order of decreasing stability least stable B C Darrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning


