
Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Question
Chapter 1, Problem 1.50QE
(a)
Interpretation Introduction
Interpretation:
The measurement of
Concept Introduction:
Rules for rounding off:
- When the last digit to be removed is more than 5, the prior number is increased by one. For example, 1.386 in which to remove 6, we have to round it to 1.39.
- When the last digit to be removed is less than 5, the prior number is not changed. For example, 4.334 if 4 is to be removed, then the result is rounded upto 4.33.
- When the last digit to be removed is 5, the prior number is not changed if it is an even number but it is increased by one if it is an odd number. For example, if 6.35 is to be rounded by removing 5, have to increase 3 to 4 giving 6.4 as the result. However, if 6.25 is to be rounded off it is rounded off to 6.2.
(b)
Interpretation Introduction
Interpretation:
The measurement of
Concept Introduction:
Refer to part (a)
(c)
Interpretation Introduction
Interpretation:
The measurement of
Concept Introduction:
Refer to part (a)
(d)
Interpretation Introduction
Interpretation:
The measurement of
Concept Introduction:
Refer to part (a)
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
dm
Re
Explanation
Check
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b) Use curved arrows to show the reaction of the radical with hydrogen bromide.
Br:
Br H
..
Answer Bank
Indicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+
Chapter 1 Solutions
Chemistry: Principles and Practice
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