Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 1, Problem 1.16QE
Interpretation Introduction
Interpretation:
The differences between accuracy and precision have to be explained and the relationship between the number of significant digits and the precision of a measurement has to be given.
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 1 Solutions
Chemistry: Principles and Practice
Ch. 1 - Define science in your own words. List three...Ch. 1 - Compare the uses of the words theory and...Ch. 1 - Explain how the coach of an athletic team might...Ch. 1 - Some scientists think the extinction of the...Ch. 1 - Prob. 1.6QECh. 1 - Define matter, mass, and weight.Ch. 1 - Matter occupies space and has mass. Are the...Ch. 1 - Give three examples of homogeneous and...Ch. 1 - Do you think it is easier to separate a...Ch. 1 - A solution made by dissolving sugar in water is...
Ch. 1 - Is the light from an electric bulb an intensive or...Ch. 1 - Are all alloys homogeneous solutions? Explain your...Ch. 1 - Prob. 1.14QECh. 1 - Prob. 1.16QECh. 1 - Describe a computation in which your calculator...Ch. 1 - Draw a block diagram (see Example 1.8) that...Ch. 1 - Prob. 1.19QECh. 1 - If you repeat the same measurement many times,...Ch. 1 - Prob. 1.21QECh. 1 - Prob. 1.23QECh. 1 - Prob. 1.24QECh. 1 - Each of the following parts contains an underlined...Ch. 1 - Prob. 1.26QECh. 1 - Classify each of the following processes as a...Ch. 1 - Classify each of the following processes as a...Ch. 1 - Prob. 1.29QECh. 1 - Prob. 1.30QECh. 1 - Prob. 1.31QECh. 1 - Prob. 1.32QECh. 1 - Prob. 1.33QECh. 1 - In the following description of the element iron,...Ch. 1 - Prob. 1.35QECh. 1 - In the following description of the element...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Classify each of the following as an element, a...Ch. 1 - Prob. 1.39QECh. 1 - Classify each of the following as an element, a...Ch. 1 - Prob. 1.41QECh. 1 - Prob. 1.42QECh. 1 - A samples true mass is 2.54 g. For each set of...Ch. 1 - A measurements true value is 17.3 g. For each set...Ch. 1 - How many significant figures are in each value?...Ch. 1 - How many significant figures are there in each of...Ch. 1 - How many significant figures are in each...Ch. 1 - How many significant figures are in each...Ch. 1 - Express the measurements to the requested number...Ch. 1 - Prob. 1.50QECh. 1 - Prob. 1.51QECh. 1 - Prob. 1.52QECh. 1 - Prob. 1.53QECh. 1 - Prob. 1.54QECh. 1 -
Perform the indicated calculations, and express...Ch. 1 - Prob. 1.56QECh. 1 - Prob. 1.57QECh. 1 - Prob. 1.58QECh. 1 - Calculate the result of the following equation,...Ch. 1 - Calculate the result of the following equation,...Ch. 1 - Prob. 1.61QECh. 1 - What base SI unit is used to express each of the...Ch. 1 - Prob. 1.63QECh. 1 - Write two conversion factors between grams (g) and...Ch. 1 - Prob. 1.65QECh. 1 - Prob. 1.66QECh. 1 - Prob. 1.67QECh. 1 - Prob. 1.68QECh. 1 - The speed of sound in air at sea level is 340 m/s....Ch. 1 -
The area of the 48 contiguous states is 3.02 ×...Ch. 1 - Prob. 1.71QECh. 1 - Prob. 1.72QECh. 1 - Prob. 1.73QECh. 1 - Prob. 1.74QECh. 1 - Prob. 1.75QECh. 1 - Prob. 1.76QECh. 1 - Wine is sold in 750-mL bottles. How many quarts of...Ch. 1 - The speed limit on limited-access roads in Canada...Ch. 1 - Prob. 1.79QECh. 1 - Many soft drinks are sold in 2.00-L containers....Ch. 1 - (a) Helium has the lowest boiling point of any...Ch. 1 - (a) The boiling point of octane is 126 C. What is...Ch. 1 - The melting point of sodium chloride, table salt,...Ch. 1 - Prob. 1.86QECh. 1 - The density of benzene at 25.0 C is 0.879 g/cm3....Ch. 1 - Ethyl acetate, one of the compounds in nail polish...Ch. 1 - Lead has a density of 11.4 g/cm3. What is the...Ch. 1 - Prob. 1.90QECh. 1 - An irregularly shaped piece of metal with a mass...Ch. 1 - A solid with an irregular shape and a mass of...Ch. 1 - How many square meters will 4.0 L (about 1 gal) of...Ch. 1 - Prob. 1.94QECh. 1 - Prob. 1.95QECh. 1 - Prob. 1.96QECh. 1 - Gold leaf, which is used for many decorative...Ch. 1 - Prob. 1.98QECh. 1 - Prob. 1.99QECh. 1 - Prob. 1.101QECh. 1 - Prob. 1.102QECh. 1 - Prob. 1.103QECh. 1 - Prob. 1.104QECh. 1 - The main weapon on a military tank is a cannon...Ch. 1 - Prob. 1.106QE
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
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