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General, Organic, and Biological Chemistry Seventh Edition
7th Edition
ISBN: 9781305767867
Author: H. Stephan Stoker
Publisher: Cengage Learning
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Textbook Question
Chapter 1, Problem 1.30EP
From the information given, classify each of the pure substances A through D as elements or compounds, or indicate that no such classification is possible because of insufficient information.
- a. Substance A cannot be broken down into simpler substances by chemical means.
- b. Substance B cannot be broken down into simpler substances by physical means.
- c. Substance C readily dissolves in water.
- d. Substance D readily reacts with the element chlorine.
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Students have asked these similar questions
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 1 Solutions
General, Organic, and Biological Chemistry Seventh Edition
Ch. 1.1 - Prob. 1QQCh. 1.1 - Which of the following is classified as matter? a....Ch. 1.1 - Prob. 3QQCh. 1.2 - Prob. 1QQCh. 1.2 - Prob. 2QQCh. 1.2 - Prob. 3QQCh. 1.3 - Prob. 1QQCh. 1.3 - Prob. 2QQCh. 1.3 - In which of the following pairs of properties are...Ch. 1.4 - Prob. 1QQ
Ch. 1.4 - Prob. 2QQCh. 1.4 - Prob. 3QQCh. 1.5 - Prob. 1QQCh. 1.5 - Prob. 2QQCh. 1.5 - Prob. 3QQCh. 1.5 - Prob. 4QQCh. 1.6 - Prob. 1QQCh. 1.6 - A compound can be separated into its constituent...Ch. 1.6 - Prob. 3QQCh. 1.6 - Prob. 4QQCh. 1.7 - Which of the following statements concerning the...Ch. 1.7 - Prob. 2QQCh. 1.7 - Prob. 3QQCh. 1.7 - Prob. 4QQCh. 1.8 - The correct chemical symbol for the element...Ch. 1.8 - Prob. 2QQCh. 1.8 - Prob. 3QQCh. 1.8 - Prob. 4QQCh. 1.9 - Prob. 1QQCh. 1.9 - Prob. 2QQCh. 1.9 - The molecules present in a compound must be a....Ch. 1.9 - Prob. 4QQCh. 1.10 - Prob. 1QQCh. 1.10 - Which of the following chemical formulas fits the...Ch. 1.10 - Which of the following pairings of chemical...Ch. 1.10 - Prob. 4QQCh. 1.10 - Prob. 5QQCh. 1.10 - Prob. 6QQCh. 1 - What are the two general characteristics that all...Ch. 1 - What are the three aspects of matter that are of...Ch. 1 - Classify each of the following as matter or energy...Ch. 1 - Classify each of the following as matter or energy...Ch. 1 - Prob. 1.5EPCh. 1 - Prob. 1.6EPCh. 1 - Indicate whether each of the following substances...Ch. 1 - Indicate whether each of the following substances...Ch. 1 - Classify each of the following properties of the...Ch. 1 - Classify each of the following properties of the...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Prob. 1.13EPCh. 1 - Classify each of the following observations about...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - Classify each of the following changes as physical...Ch. 1 - Prob. 1.17EPCh. 1 - Classify each of the following changes as physical...Ch. 1 - Correctly complete each of the following sentences...Ch. 1 - Correctly complete each of the following sentences...Ch. 1 - Classify each of the following as (1) a physical...Ch. 1 - Classify each of the following as (1) a physical...Ch. 1 - Classify each of the following statements as true...Ch. 1 - Classify each of the following statements as true...Ch. 1 - Prob. 1.25EPCh. 1 - Assign each of the following descriptions of...Ch. 1 - Classify each of the following as a heterogeneous...Ch. 1 - Classify each of the following as a heterogeneous...Ch. 1 - From the information given, classify each of the...Ch. 1 - From the information given, classify each of the...Ch. 1 - Prob. 1.31EPCh. 1 - From the information given in the following...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Consider two boxes with the following contents:...Ch. 1 - Consider two boxes with the following contents:...Ch. 1 - Assign each of the following descriptions of...Ch. 1 - Assign each of the following descriptions of...Ch. 1 - Indicate whether each of the following samples of...Ch. 1 - Indicate whether each of the following samples of...Ch. 1 - Indicate whether each of the following...Ch. 1 - Indicate whether each of the following...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Prob. 1.45EPCh. 1 - Indicate whether each of the following statements...Ch. 1 - Prob. 1.47EPCh. 1 - Prob. 1.48EPCh. 1 - Give the name of the element denoted by each of...Ch. 1 - Prob. 1.50EPCh. 1 - Prob. 1.51EPCh. 1 - Prob. 1.52EPCh. 1 - Write the chemical symbol for each member of the...Ch. 1 - Write the chemical symbol for each member of the...Ch. 1 - In which of the following sequences of elements do...Ch. 1 - In which of the following sequences of elements do...Ch. 1 - Classify the substances represented by the...Ch. 1 - Classify the substances represented by the...Ch. 1 - Classify the substances represented by the models...Ch. 1 - Classify the substances represented by the models...Ch. 1 - Classify the substances represented by the models...Ch. 1 - Classify the substances represented by the models...Ch. 1 - Assign each of the following molecular...Ch. 1 - Assign each of the following molecular...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - Indicate whether each of the following statements...Ch. 1 - In the following diagrams, the different colored...Ch. 1 - In the following diagrams, different colored...Ch. 1 - Assign each of the following descriptions of...Ch. 1 - Assign each of the following descriptions of...Ch. 1 - In the following diagram, the different colored...Ch. 1 - Using the diagrams given in problem 1-71, select...Ch. 1 - Write chemical formulas for the substances...Ch. 1 - Write chemical formulas for the substances...Ch. 1 - Prob. 1.75EPCh. 1 - Prob. 1.76EPCh. 1 - Prob. 1.77EPCh. 1 - Prob. 1.78EPCh. 1 - Write all possible chemical formulas for a...Ch. 1 - Write all possible chemical formulas for a...Ch. 1 - Write a chemical formula for each of the following...Ch. 1 - Write a chemical formula for each of the following...Ch. 1 - Prob. 1.83EPCh. 1 - Prob. 1.84EPCh. 1 - On the basis of the given information, determine...Ch. 1 - On the basis of the information given, determine...Ch. 1 - Prob. 1.87EPCh. 1 - A mixture contains the following five pure...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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