Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 1, Problem 1.19NP
Interpretation Introduction

Interpretation:The pressure exerted by benzene for a molar volume of 2.00 L at 595 K with the help of Redlich-Kwong equation of state needs to be determined. Under these conditions, whether the attractive or repulsive portion of the potential dominant needs to be determined.

Concept Introduction: The ideal gas equation is the equation which gives the relations between P,V, n and T of gases. It can be written as:

  PV = nRT

Here, P is pressure, V is volume, n is number of moles, R is Universal gas constant and T is temperature.

The Redlich-Kwong equation is represented as follows:

  P = R TVm-b -  aTVm (Vm+ b)P = n R TV - nb -  n2aTV (V + nb)

Here, a and b are constants.

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