Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Textbook Question
Chapter 1, Problem 1.18A
APPLY 1.18 How large, in cubic centimeters, is the volume of a red blood cell (in cm3) if the cell has a cylindrical shape with a diameter of 6 × 10-6 m and a height of 2 × 10-6 m? What is the volume in pL?
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206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
5.
Please consider the Newman projection of tartaric acid drawn below as an eclipsed
conformer (1). Please draw the most stable conformer and two intermediate energy conformers
noting that staggered conformers are lower in energy than eclipsed forms even if the staggered
conformers have gauche relationships between groups. [Draw the substituents H and OH on the front
carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.]
OH
COH
ICOOH
COOH
COOH
1
2
COOH
COOH
3
4
Staggered
Staggered
Staggered (most stable)
Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies
below.
Ref=0
Rotation
6. (60 points)
a. Are compounds 1 and 2 below enantiomers, diastereomers or identical?
OH
OH
HO
HO
LOH
HO
HO
OH
2
OH
OH
b. Please complete the zig-zag conformation of the compound
(3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes.
3.
Chapter 1 Solutions
Chemistry (7th Edition)
Ch. 1 - PRACTICE 1.1 Express the following quantities in...Ch. 1 - APPLY 1.2 Express the following quantities in...Ch. 1 - PRACTICE 1.3 The melting point of table salt is...Ch. 1 - Prob. 1.4ACh. 1 - PRACTICE 1.5 Chloroform, a substance once used as...Ch. 1 - APPLY 1.6 You are beachcombing on summer vacation...Ch. 1 - PRACTICE 1.7 Some radioactive materials emit a...Ch. 1 - Prob. 1.8ACh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10A
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12ACh. 1 - Prob. 1.13PCh. 1 - APPLY 1.14 A sodium chloride solution was prepared...Ch. 1 - PRACTICE 1.15 Gemstones are weighed in carats,...Ch. 1 - PRACTICE 1.15 Gemstones are weighed in carats,...Ch. 1 - Prob. 1.17PCh. 1 - APPLY 1.18 How large, in cubic centimeters, is the...Ch. 1 - Prob. 1.19PCh. 1 - PROBLEM 1.20 Calculate the percentage Of atoms on...Ch. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Which block in each of the following drawings of a...Ch. 1 - Prob. 1.24CPCh. 1 - How many milliliters of water does the graduated...Ch. 1 - Assume that you have two graduated cylinders, one...Ch. 1 - The following cylinder contains three liquids that...Ch. 1 - The following statements pertain to the...Ch. 1 - The following statements pertain to the...Ch. 1 - Prob. 1.30SPCh. 1 - Prob. 1.31SPCh. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Prob. 1.34SPCh. 1 - Prob. 1.35SPCh. 1 - 1.36 What is the difference between mass and...Ch. 1 - Prob. 1.37SPCh. 1 - Prob. 1.38SPCh. 1 - Prob. 1.39SPCh. 1 - Prob. 1.40SPCh. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - Prob. 1.45SPCh. 1 - Prob. 1.46SPCh. 1 - Prob. 1.47SPCh. 1 - Prob. 1.48SPCh. 1 - Prob. 1.49SPCh. 1 - How many picograms are in 1 mg? In 35 ng?Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - Prob. 1.53SPCh. 1 - How many significant figures are in each of the...Ch. 1 - Prob. 1.55SPCh. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Prob. 1.58SPCh. 1 - Prob. 1.59SPCh. 1 - Prob. 1.60SPCh. 1 - Prob. 1.61SPCh. 1 - Prob. 1.62SPCh. 1 - Prob. 1.63SPCh. 1 - Prob. 1.64SPCh. 1 - Prob. 1.65SPCh. 1 - Carry Out the following conversions: (a) How many...Ch. 1 - Prob. 1.67SPCh. 1 - Prob. 1.68SPCh. 1 - Prob. 1.69SPCh. 1 - Weights in England are commonly measured in...Ch. 1 - Prob. 1.71SPCh. 1 - Prob. 1.72SPCh. 1 - Prob. 1.73SPCh. 1 - The normal body temperature of a goat is 39.90C...Ch. 1 - Prob. 1.75SPCh. 1 - Prob. 1.76SPCh. 1 - Prob. 1.77SPCh. 1 - Suppose you were dissatisfied with both Celsius...Ch. 1 - Answer parts (a)-(d) of Problem 1.78 assuming that...Ch. 1 - Prob. 1.80SPCh. 1 - Prob. 1.81SPCh. 1 - Prob. 1.82SPCh. 1 - Prob. 1.83SPCh. 1 - Prob. 1.84SPCh. 1 - The density Of silver is 10.5 g/cm3. What is the...Ch. 1 - Prob. 1.86SPCh. 1 - Prob. 1.87SPCh. 1 - Prob. 1.88SPCh. 1 - An experiment is performed to determine if pennies...Ch. 1 - Which has more kinetic energy, a 1400 kg car...Ch. 1 - Prob. 1.91SPCh. 1 - Prob. 1.92SPCh. 1 - Prob. 1.93SPCh. 1 - Prob. 1.94SPCh. 1 - Prob. 1.95SPCh. 1 - Prob. 1.96CPCh. 1 - Lignum vitae is a hard, durable, and extremely...Ch. 1 - Prob. 1.98CPCh. 1 - Prob. 1.99CPCh. 1 - Prob. 1.100CPCh. 1 - Prob. 1.101CPCh. 1 - Answer the following questions: (a) An old rule of...Ch. 1 - A 1.0 ounce piece of chocolate contains 15 mg of...Ch. 1 - Prob. 1.104CPCh. 1 - Prob. 1.105CPCh. 1 - Prob. 1.106CPCh. 1 - Prob. 1.107CPCh. 1 - Prob. 1.108CPCh. 1 - Prob. 1.109CPCh. 1 - Prob. 1.110CPCh. 1 - Prob. 1.111CPCh. 1 - Brass is a copper—zinc alloy. What is the mass in...Ch. 1 - Prob. 1.113CPCh. 1 - The element gallium (Ga) has the second largest...Ch. 1 - Distances over land are measured in statute miles...
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