Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Textbook Question
Chapter 0, Problem 21RQ
How was the charge-to-mass ratio of the electron determined?
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What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 0 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 0 - Practice Exercise 0.1
Using the chapter titles...Ch. 0 - Prob. 2PECh. 0 - Prob. 3PECh. 0 - Prob. 4PECh. 0 - Prob. 5PECh. 0 - Prob. 6PECh. 0 - Prob. 7PECh. 0 - Prob. 8PECh. 0 - Prob. 9PECh. 0 - Practice Exercise 0.10 Aluminum atoms have a mass...
Ch. 0 - Practice Exercise 0.11 How much heavier is the...Ch. 0 - Practice Exercise 0.12 The definition of the size...Ch. 0 - Practice Exercise 0.13 Naturally occurring boron...Ch. 0 - Practice Exercise 0.14
Neon, the gas used in neon...Ch. 0 - Prob. 1RQCh. 0 - 0.2 Knowing what we know today, which of the...Ch. 0 - 0.3 In what ways does the atomic theory affect the...Ch. 0 - Shake a few crystals of salt into your hand and...Ch. 0 - Are there any examples of crystals in nature that...Ch. 0 - 0.6 Heat is one form of energy. If a reaction...Ch. 0 - Can you think of a chemical reaction that starts...Ch. 0 - 0.8 Some large biological molecules rely on...Ch. 0 - 0.9 What elements were formed (a) during the first...Ch. 0 - Prob. 10RQCh. 0 - 0.11 What is the predominant element in the solar...Ch. 0 - Prob. 12RQCh. 0 - What physical factors caused elements and minerals...Ch. 0 - Is this separation still occurring on the earth?Ch. 0 - 0.15 What measuring devices did early chemists...Ch. 0 - 0.16 In your own words, describe how Daltons...Ch. 0 - Which of the laws of chemical combination is used...Ch. 0 - Prob. 18RQCh. 0 - Where in an atom is nearly all of its mass...Ch. 0 - What is a nucleon? Which ones have we studied?Ch. 0 - 0.21 How was the charge-to-mass ratio of the...Ch. 0 - 0.22 How did Robert Millikan determine the charge...Ch. 0 - How was the proton discovered?Ch. 0 - What experiment did Rutherford carry out to...Ch. 0 - Why dont we count the electrons when determining...Ch. 0 - Define the terms atomic number and mass number....Ch. 0 - Prob. 27RQCh. 0 - Write the symbols of the isotopes that contain the...Ch. 0 - What is wrong with the following statement? The...Ch. 0 - 0.30 The atomic number of silver, Ag, is 47 and it...Ch. 0 - A certain element X forms a compound with oxygen...Ch. 0 - Nitrogen reacts with a metal to form a compound in...Ch. 0 - Give the numbers of neutrons, protons, and...Ch. 0 - 0.34 Give the numbers of electrons, protons, and...Ch. 0 - Iodine-131 is used to treat overactive thyroids;...Ch. 0 - Prob. 36RQCh. 0 - 0.37 One chemical substance in natural gas is a...Ch. 0 - 0.38 Carbon tetrachloride contains one carbon and...Ch. 0 - If an atom of carbon-12 had been assigned a...Ch. 0 - 0.40 One atom of has a mass that is 9.0754 times...Ch. 0 - Naturally occurring copper is composed of 69.17%...Ch. 0 - Naturally occurring magnesium (one of the elements...Ch. 0 - N2O is often called nitrous oxide or laughing gas,...Ch. 0 - An element has 24 protons in its nucleus. (a)...Ch. 0 - Iron is composed of four isotopes with the...Ch. 0 - 0.46 What color are the protons, neutrons, and...Ch. 0 - 0.47 Immediately after the big bang, helium and...Ch. 0 - Prob. 48RQCh. 0 - Scientists often validate measurements, such as...Ch. 0 - Sir James Chadwick, discovered the neutron. The...
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