You want to store 137 g of CO₂ gas in a 15.3- L tank at room temperature (25 °C). Calculate the pressure the gas would have using the ideal gas law and the van der Waals equation. (For CO₂, a = 3.59 atm. L²/mol² and b = 0.0427 L/mol.) Pideal atm = PvdW = atm

You want to store 137 g of CO₂ gas in a 15.3- L tank at room temperature (25 °C). Calculate the pressure the gas would have using the ideal gas law and the van der Waals equation. (For CO₂, a = 3.59 atm. L²/mol² and b = 0.0427 L/mol.) Pideal atm = PvdW = atm

Introductory Chemistry: A Foundation

8th Edition

ISBN:9781285199030

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter13: Gases

Section: Chapter Questions

Problem 138AP: A mixture at 33 °C contains H2at 325 torr. N;at 475 tore and O2at 650. torr. What is the total...

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A chemist weighed out 5.14 g of a mixture containing unknown amounts of BaO(s) and CaO(s) and placed the sample in a 1.50-L flask containing CO2(g) at 30.0C and 750. torr. After the reaction to form BaCO3(s) and CaCO3(s) was completed, the pressure of CO2(g) remaining was 230. torr. Calculate the mass percentages of CaO(s) and BaO(s) in the mixture.
A mixture at 33 °C contains H2at 325 torr. N;at 475 tore and O2at 650. torr. What is the total pressure of the gases in the system? Which gas contains the greatest number of moles?
If equal masses of O2 and N2 are placed in separate containers of equal volume at the same temperature, which of the following statements is true? If false, explain why it is false. (a) The pressure in the flask containing N2 is greater than that in the flask containing O2. (b) There are more molecules in the flask containing O2 than in the flask containing N2.
Butyl mercaptan, C4H9SH, has a very bad odor and is among the compounds added to natural gas to help detect a leak of otherwise odorless natural gas. In an experiment, you burn 95.0 mg of C4H9SH and collect the product gases (SO2, CO2, and H2O) in a 5.25-L flask at 25 C. What is the total gas pressure in the flask, and what is the partial pressure of each of the product gases?
You have an equimolar mixture of the gases SO2 and O2, along with some He, in a container fitted with a piston. The density of this mixture at STP is 1.924 g/L. Assume ideal behavior and constant temperature and pressure. a. What is the mole fraction of He in the original mixture? b. The SO2 and O2 react to completion to form SO3. What is the density of the gas mixture after the reaction is complete?
Hydrogen gas is used in weather balloon because it is less expensive than Helium. Assume that 5.57 g of H2 is used to fill a weather balloon to an initial volume of 67 L at 1.04 atm. If the ballloon rises to an altitude where the pressure is 0.047 atm, what is its new volume? Assume that the temperature remains constant.
You have a 550.-mL tank of gas with a pressure of 1.56 atm at 24 C. You thought the gas was pure carbon monoxide gas, CO, but you later found it was contaminated by small quantities of gaseous CO2 and O2. Analysis shows that the tank pressure is 1.34 atm (at 24 C) if the CO2 is removed. Another experiment shows that 0.0870 g of O2 can be removed chemically. What are the masses of CO and CO2 in the tank, and what is the partial pressure of each of the three gases at 25 C?
Many nitrate salts can be decomposed by heating. For example, blue, anhydrous copper(II) nitrate produces the gases nitrogen dioxide and oxygen when heated. In the laboratory, you find that a sample of this salt produced a 0.195-g mixture of gaseous NO2 and O2 with a total pressure of 725 mm Hg at 35 C in a 125-mL flask (and black, solid CuO was left as a residue). What is the average molar mass of the gas mixture? What are the mole fractions of NO2 and O2 in the mixture? What amount of each gas b in the mixture? Do these amounts reflect the relative amounts of NO2 and O2 expected based on the balanced equation? Is it possible that the fact that some NO2 molecules combine to give N2O4 plays a role? Heating copper(II) nitrate produces nitrogen dioxide and oxygen gas and leaves a residue of copper(ll) oxide.
Plot the data given in Table 5.3 for oxygen at 0C to obtain an accurate molar mass for O2. To do this, calculate a value of the molar mass at each of the given pressures from the ideal gas law (we will call this the apparent molar mass at this pressure). On a graph show the apparent molar mass versus the pressure and extrapolate to find the molar mass at zero pressure. Because the ideal gas law is most accurate at low pressures, this extrapolation will give an accurate value for the molar mass. What is the accurate molar mass?
47 HCl(g) reacts with ammonia gas, NH3(g), to form solid ammonium chloride. If a sample of ammonia occupying 250 mL at 21 C and a pressure of 140 torr is allowed to react with excess HCl, what mass of NH4Cl will form?
99 Pure gaseous nitrogen dioxide (NO2) cannot be obtained, because NO2dimerizes, or combines with itself, to produce a mixture of NO2 and N2O4. A particular mixture of NO2, and N2O4 has a density of 2.39 g/L at 50°C and 745 torr. What is the partial pressure of NO2 in this mixture?
93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)