You dilute 1g of an orgainc liquid, with ethanol, to 10mL in a volumertic flask. This solution is analyzed using polarimerty (at 20oC), and an optical rotation of -6.8o is observed. Calculate the specific rotation of the oraginc liquid, if the sample cell that was used was 100mm.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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You dilute 1g of an orgainc liquid, with ethanol, to 10mL in a volumertic flask. This solution is analyzed using polarimerty (at 20oC), and an optical rotation of -6.8is observed. Calculate the specific rotation of the oraginc liquid, if the sample cell that was used was 100mm. 

Expert Solution
Step 1

The formula for finding specific rotation is ,

αD=αC×L

Where αD is the specific rotation, α is the optical rotation, C and L are concentration in g/mL and pathlength in dm.  

Given values,

α=-6.80

mass of organic liquid = 1g

volume of solution =10 mL

Pathlength = 100 mm

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