You and a colleague are performing freezing-point depression experiments with standard concentrated and dilute solutions of KNO3 in water. If you assume i = 2 for the ionic compound, all your data makes sense for dilute solutions. But when your colleague measures data for a concentrated solution, she concludes that i = 1.5. Suggest an explanation. O Your colleague must be doing something wrong; i is always an integer. O At high concentrations, it is possible that ion pairs form in solution, such as K*---NO, which acts like one "particle" instead of two, thereby reducing the van't Hoff factor. O Freezing-point depression is only valid for dilute solutions, so your colleague should throw out the data for concentrated solutions. O The nitrate anion is reacting with water, so the number of ions in solution is actually decreasing at high concentrations. O Your colleague should just round 1.5 to 2.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Part A
You and a colleague are performing freezing-point depression experiments with standard concentrated and dilute solutions of KNO3 in water. If you assume i = 2 for the ionic compound, all your data
makes sense for dilute solutions. But when your colleague measures data for a concentrated solution, she concludes that i = 1.5. Suggest an explanation.
Your colleague must be doing something wrong; i is always an integer.
O At high concentrations, it is possible that ion pairs form in solution, such as K*---NO3, which acts like one "particle" instead of two, thereby reducing the van't Hoff factor.
Freezing-point depression is only valid for dilute solutions, so your colleague should throw out the data for concentrated solutions.
The nitrate anion is reacting with water, so the number of ions in solution is actually decreasing at high concentrations.
Your colleague should just round 1.5 to 2.
O O O
Transcribed Image Text:Part A You and a colleague are performing freezing-point depression experiments with standard concentrated and dilute solutions of KNO3 in water. If you assume i = 2 for the ionic compound, all your data makes sense for dilute solutions. But when your colleague measures data for a concentrated solution, she concludes that i = 1.5. Suggest an explanation. Your colleague must be doing something wrong; i is always an integer. O At high concentrations, it is possible that ion pairs form in solution, such as K*---NO3, which acts like one "particle" instead of two, thereby reducing the van't Hoff factor. Freezing-point depression is only valid for dilute solutions, so your colleague should throw out the data for concentrated solutions. The nitrate anion is reacting with water, so the number of ions in solution is actually decreasing at high concentrations. Your colleague should just round 1.5 to 2. O O O
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