Write the reactions involved for each step in the Winkler method. Under alkaline conditions dissolved oxygen will oxidize manganese (II) ions to manganese (IV). Under acidic conditions, the MnO2 oxidizes the iodide (I-) to free iodine (I2). Reduction of iodine to iodide with thiosulfate.

Chemistry: Principles and Practice
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Chapter18: Electrochemistry
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Problem 18.57QE
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Write the reactions involved for each step in the Winkler method. 

  1. Under alkaline conditions dissolved oxygen will oxidize manganese (II) ions to manganese (IV).
  2. Under acidic conditions, the MnO2 oxidizes the iodide (I-) to free iodine (I2).
  3. Reduction of iodine to iodide with thiosulfate.

 

 



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