Write the overall reaction and the rate laws that corre- spond to the following reaction mechanisms. Be sure to eliminate intermediates from the answers. (a) 2 A + B = D (fast equilibrium) k-s k2 D + B → E + F (slow) ks F , G (fast) (b) A + B= C (fast equilibrium) k2 C+D 2 F k-2 (fast equilibrium) k F , G (slow)
Write the overall reaction and the rate laws that corre- spond to the following reaction mechanisms. Be sure to eliminate intermediates from the answers. (a) 2 A + B = D (fast equilibrium) k-s k2 D + B → E + F (slow) ks F , G (fast) (b) A + B= C (fast equilibrium) k2 C+D 2 F k-2 (fast equilibrium) k F , G (slow)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Write the overall reaction and the rate laws that corre-
spond to the following reaction mechanisms. Be sure to
eliminate intermediates from the answers.
(a) 2 A + B = D
(fast equilibrium)
k-s
k2
D + B → E + F
(slow)
ks
F , G
(fast)
(b) A + B= C
(fast equilibrium)
k2
C+D 2 F
k-2
(fast equilibrium)
k
F , G
(slow)
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