Write the overall equation for the process assuming a one electron transfer takes Page 3 It is thought that the reduction of [Fe(phen);+ by [Fe(CN)6]" a. most likely occurs via an outer-sphere mechanism. i. place. ii. Write out, with annotations, the mechanism for the reaction. The redox couples for the half equations below are involved in the terminal respiratory chain. b. FAD + 2H + 2e FADH2 NAD* + 2H* + 2e NADH + H* E" = -0.219 V E" = -0.320 V Write the chemical equation that is most likely to occur between the NAD*|NADH and the FAD FADH redox couples. Hence, calculate the electrode potential of the overall reaction. i. ii. Calculate AG and K for the reaction at 25 °C. The standard reduction potential of the Fe"(aq) Fe (aq) couple is 0.77 V. When ligand L is incorporated in the iron complexes the redox potential becomes 1.02 V. Determine whether ligand L is most likely to с. be classified a T-donor a as or T-acceptor. Give a full account of your reasoning.

Write the overall equation for the process assuming a one electron transfer takes Page 3 It is thought that the reduction of [Fe(phen);+ by [Fe(CN)6]" a. most likely occurs via an outer-sphere mechanism. i. place. ii. Write out, with annotations, the mechanism for the reaction. The redox couples for the half equations below are involved in the terminal respiratory chain. b. FAD + 2H + 2e FADH2 NAD* + 2H* + 2e NADH + H* E" = -0.219 V E" = -0.320 V Write the chemical equation that is most likely to occur between the NAD*|NADH and the FAD FADH redox couples. Hence, calculate the electrode potential of the overall reaction. i. ii. Calculate AG and K for the reaction at 25 °C. The standard reduction potential of the Fe"(aq) Fe (aq) couple is 0.77 V. When ligand L is incorporated in the iron complexes the redox potential becomes 1.02 V. Determine whether ligand L is most likely to с. be classified a T-donor a as or T-acceptor. Give a full account of your reasoning.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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