While investigating the properties of other diatomic molecules, the student finds the diagram below, which shows the potential energy of two iodine atoms versus the distance between their nuclei. The student also finds that the I - I bond energy is slightly less than the F – F bond energy. The student incorrectly sketches the potential energy curve for two fluorine atoms, shown by the dotted line in the diagram. 200- 100- E一 200 600 1100 300 400 500 700 800 -100+ -200- Internuclear Distance (pm) (h) Explain the error with the student's sketch for F2(g). Potential Energy (kJ/mol)
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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![While investigating the properties of other diatomic molecules, the student finds the diagram below, which shows the potential energy of two iodine atoms versus the distance between their nuclei. The student also finds
that the I- I bond energy is slightly less than the F – F bond energy. The student incorrectly sketches the potential energy curve for two fluorine atoms, shown by the dotted line in the diagram.
200
100
200
600
300.
400 500
1100
700 800
-100
-200
Internuclear Distance (pm)
(h) Explain the error with the student's sketch for F2(g).
Potential Energy (kJ/mol)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6648b57a-6726-40e7-86cc-a0bb06f0c82a%2F5bb742ec-d491-42d1-a14c-59b559aee88c%2Fcgk8eo_processed.png&w=3840&q=75)
![An unknown gas, D, reacts with fluorine gas to form the compound DF4(g), as represented by the following equation.
D(g) + 2 F2(9) → DF4(9)
A series of experimental trials were performed at 600°C to determine the rate law expression for the reaction. Data from the trials are shown below.
Initial Pp
Initial PF2
Initial Rate of Appearance of DF,(9)
(torr)
(torr)
(torr/min)
Trial 1
1500
1500
5.00 x 10–3
Trial 2
3000
1500
10.0 x 10-3
Trial 3
1500
3000
20.0 x 10–3](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6648b57a-6726-40e7-86cc-a0bb06f0c82a%2F5bb742ec-d491-42d1-a14c-59b559aee88c%2F6t2d9ym_processed.png&w=3840&q=75)
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