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Which two of the following statements relating to the reaction shown below are correct? Ph ✪ HHO + Ph 60 °C Ph KHÍ KO = 2.87 This is a primary kinetic isotope effect. This is a secondary kinetic isotope effect. The C-H/D bond is broken in the rate-determining step. The C-H/D bond is not broken in the rate-determining step. It can be concluded that the C-N bond is broken in the rds.

Which two of the following statements relating to the reaction shown below are correct? Ph ✪ HHO + Ph 60 °C Ph KHÍ KO = 2.87 This is a primary kinetic isotope effect. This is a secondary kinetic isotope effect. The C-H/D bond is broken in the rate-determining step. The C-H/D bond is not broken in the rate-determining step. It can be concluded that the C-N bond is broken in the rds.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Which two of the following statements relating to the reaction shown below are correct? Ph HH Ph 60 °C Ph KHÍ KO = 2.87 This is a primary kinetic isotope effect. This is a secondary kinetic isotope effect. The C-H/D bond is broken in the rate-determining step. The C-H/D bond is not broken in the rate-determining step. It can be concluded that the C-N bond is broken in the rds.
Transcribed Image Text:Which two of the following statements relating to the reaction shown below are correct? Ph HH Ph 60 °C Ph KHÍ KO = 2.87 This is a primary kinetic isotope effect. This is a secondary kinetic isotope effect. The C-H/D bond is broken in the rate-determining step. The C-H/D bond is not broken in the rate-determining step. It can be concluded that the C-N bond is broken in the rds.
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Primary kinetic isotope effect: C-H bond is broken in rate determining step (rds)

KH/D is greater than 1 in primary isotope effect

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