Which structure is consistent with the IR spectrum? LOD TRANSMITTANCEI D 4000 (a) (b) 3000 (d) (e) 2000 HAVENURBERI-1 НО. "OXY OH 1500 H 1000 500

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Molecular Structure Identification

The image provided contains six molecular structures labeled from (a) to (f). Below each structure, there is a corresponding radio button option for selection.

#### Molecular Structures:
1. **(a)** 
   - Structure: Contains a double bond between two carbon atoms attached to a carbonyl group (an acetyl group).
   - Chemical representation: 
     ```
      CH2=CH-CO-CH2
     ```
2. **(b)**
   - Structure: Consists of a benzene ring fused with a six-membered ring containing an oxygen atom, known as a benzopyranone.
   - Chemical representation: 
     ```
     (benzene ring)-O-(six-membered ring)
     ```
3. **(c)**
   - Structure: Contains a carbonyl group (ketone) with a three-carbon chain.
   - Chemical representation:
     ```
      CH3-CH2-CO-CH3
     ```
4. **(d)**
   - Structure: A bicyclic ketone with an additional oxygen.
   - Chemical representation:
     ```
     HO-C-O-CO-CH3
     ```
5. **(e)**
   - Structure: A cyclohexane ring with an alcohol (-OH) group attached.
   - Chemical representation:
     ```
     (cyclohexane ring)-OH
     ```
6. **(f)**
   - Structure: Contains a benzene ring with an attached aldehyde group.
   - Chemical representation:
     ```
      C6H5-CHO
     ```

#### Option Selection:
- Users are given options to select one of the structures (a, b, c, d, e, f) using radio buttons.

#### Explanation of any Graphs or Diagrams:
There are no graphs or diagrams provided in the image. The main focus is on the molecular structures.

This educational material is useful for students or professionals in chemistry to practice identifying and understanding different organic molecular structures.
Transcribed Image Text:### Molecular Structure Identification The image provided contains six molecular structures labeled from (a) to (f). Below each structure, there is a corresponding radio button option for selection. #### Molecular Structures: 1. **(a)** - Structure: Contains a double bond between two carbon atoms attached to a carbonyl group (an acetyl group). - Chemical representation: ``` CH2=CH-CO-CH2 ``` 2. **(b)** - Structure: Consists of a benzene ring fused with a six-membered ring containing an oxygen atom, known as a benzopyranone. - Chemical representation: ``` (benzene ring)-O-(six-membered ring) ``` 3. **(c)** - Structure: Contains a carbonyl group (ketone) with a three-carbon chain. - Chemical representation: ``` CH3-CH2-CO-CH3 ``` 4. **(d)** - Structure: A bicyclic ketone with an additional oxygen. - Chemical representation: ``` HO-C-O-CO-CH3 ``` 5. **(e)** - Structure: A cyclohexane ring with an alcohol (-OH) group attached. - Chemical representation: ``` (cyclohexane ring)-OH ``` 6. **(f)** - Structure: Contains a benzene ring with an attached aldehyde group. - Chemical representation: ``` C6H5-CHO ``` #### Option Selection: - Users are given options to select one of the structures (a, b, c, d, e, f) using radio buttons. #### Explanation of any Graphs or Diagrams: There are no graphs or diagrams provided in the image. The main focus is on the molecular structures. This educational material is useful for students or professionals in chemistry to practice identifying and understanding different organic molecular structures.
**IR Spectrum Analysis and Structural Identification**

In infrared (IR) spectroscopy, molecular vibrations are measured, providing insights into the chemical structure of a compound. Below is an IR spectrum chart along with several possible molecular structures. The goal is to determine which of these structures is consistent with the provided IR spectrum.

### IR Spectrum Analysis

**Graph Explanation:**
- The X-axis represents the wavenumber in cm⁻¹, ranging from 4000 to 500.
- The Y-axis represents the transmittance percentage (%), with 100% at the top and 0% at the bottom.
- Key peaks and valleys in the spectrum correspond to the vibrational frequencies of different chemical bonds. 

### Potential Structures for Identification

Below the spectrum, there are six possible molecular structures labeled (a) through (f):

1. **Structure (a)** - Contains an alkyne group (C≡C) and a carbonyl group (C=O).
2. **Structure (b)** - Features a bicyclic structure with an ether group (C-O-C).
3. **Structure (c)** - Appears to be a cyclic compound with a conjugated system.
4. **Structure (d)** - An ester (RCOOR’) with a linear chain.
5. **Structure (e)** - Contains a cyclohexane ring with a hydroxyl group (OH) attached.
6. **Structure (f)** - Features a cyclohexane ring with an aldehyde group (CHO).

### Identifying Key Peaks

To identify the consistent structure:
- Peaks around **3400 cm⁻¹** often indicate O-H or N-H stretches.
- Peaks around **1700 cm⁻¹** typically correlate with C=O stretches in carbonyl compounds.
- C≡C stretches usually appear near **2100-2260 cm⁻¹**.
- C-H stretches can be identified around **2850-2970 cm⁻¹**.

By analyzing these characteristic peaks and comparing them to the structures provided, one can identify the structure that matches the IR spectrum.

*Note: This exercise is intended to help students understand the process of structural determination using IR spectroscopy.*
Transcribed Image Text:**IR Spectrum Analysis and Structural Identification** In infrared (IR) spectroscopy, molecular vibrations are measured, providing insights into the chemical structure of a compound. Below is an IR spectrum chart along with several possible molecular structures. The goal is to determine which of these structures is consistent with the provided IR spectrum. ### IR Spectrum Analysis **Graph Explanation:** - The X-axis represents the wavenumber in cm⁻¹, ranging from 4000 to 500. - The Y-axis represents the transmittance percentage (%), with 100% at the top and 0% at the bottom. - Key peaks and valleys in the spectrum correspond to the vibrational frequencies of different chemical bonds. ### Potential Structures for Identification Below the spectrum, there are six possible molecular structures labeled (a) through (f): 1. **Structure (a)** - Contains an alkyne group (C≡C) and a carbonyl group (C=O). 2. **Structure (b)** - Features a bicyclic structure with an ether group (C-O-C). 3. **Structure (c)** - Appears to be a cyclic compound with a conjugated system. 4. **Structure (d)** - An ester (RCOOR’) with a linear chain. 5. **Structure (e)** - Contains a cyclohexane ring with a hydroxyl group (OH) attached. 6. **Structure (f)** - Features a cyclohexane ring with an aldehyde group (CHO). ### Identifying Key Peaks To identify the consistent structure: - Peaks around **3400 cm⁻¹** often indicate O-H or N-H stretches. - Peaks around **1700 cm⁻¹** typically correlate with C=O stretches in carbonyl compounds. - C≡C stretches usually appear near **2100-2260 cm⁻¹**. - C-H stretches can be identified around **2850-2970 cm⁻¹**. By analyzing these characteristic peaks and comparing them to the structures provided, one can identify the structure that matches the IR spectrum. *Note: This exercise is intended to help students understand the process of structural determination using IR spectroscopy.*
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