Which resonance form contributes more to the resonance hybrid? Explain briefly. N-H H- CH3 H-ö CH3 Which of the following is NOT a resonance form of the compound given above? CH3 Y CH3 A) A) X because carbon better handles + charge (C less electronegative) B) B) Y because oxygen better handles + charge (O more electronegative) C) Y because oxygen better handles + charge (O is larger). N-H D) X because Y is missing an octet. D) E) Y because X is missing an octet. Identify the hybridization for cach of the following indicated atoms. Which of the following is the most accurate 3-Drepresentation of phenylacetylene. (lgnore resonance delkocalization; sketch just the discreet Lewis structure piven below.) H-O-H ÇECH A) sp sp phenylacetylene B) sp C) sp sp D) sp? sp? ĐAll of the above are accurate 3-D sketiches sp
Electronic Effects
The effect of electrons that are located in the chemical bonds within the atoms of the molecule is termed an electronic effect. The electronic effect is also explained as the effect through which the reactivity of the compound in one portion is controlled by the electron repulsion or attraction producing in another portion of the molecule.
Drawing Resonance Forms
In organic chemistry, resonance may be a mental exercise that illustrates the delocalization of electrons inside molecules within the valence bond theory of octet bonding. It entails creating several Lewis structures that, when combined, reflect the molecule's entire electronic structure. One Lewis diagram cannot explain the bonding (lone pair, double bond, octet) elaborately. A hybrid describes a combination of possible resonance structures that represents the entire delocalization of electrons within the molecule.
Using Molecular Structure To Predict Equilibrium
Equilibrium does not always imply an equal presence of reactants and products. This signifies that the reaction reaches a point when reactant and product quantities remain constant as the rate of forward and backward reaction is the same. Molecular structures of various compounds can help in predicting equilibrium.
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Which resonance form contributes more to
the resonance hybrid? Explain briefly.
N-H
„CH3
H-ö.
CH3
Which of the following is NOT a resonance
form of the compound given above?
ČH3
Y
CH3
A)
N-H
A) X because carbon better handles
+ charge (C less electronegative)
В)
B) Y because oxygen better handles
+ charge (O more electronegative)
`N-H
C) Y because oxygen better handles
+ charge (O is larger).
C)
N-H
D) X because Y is missing an octet.
D)
N-H
E) Y because X is missing an octet.
*1
Identify the hybridization for each of the following indicated atoms.
Which of the t
(Ignore re iowing is the moug
sketch just the discreet Lewis structure given below.)
H-O-H
CH,CCH,
ÇECH
A)
sp
sp
sp
phenylacetylene
B)
sp?
sp
sp
B)
C)
C)
sp
sp
sp
D)
sp
sp
sp2
E)
sp
sp
E) All of the above are accurate 3-D sketches
Sp2
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D)
sp
sp3
sp?
E)
sp2
sp2
sp?
E) All of the above are accurate 3-D sketches.
Identify each of the lone pairs in
fentanyl as localized or delocalized.
Identify the orbital occupied by the lone pair on
each of the indicated nitrogen atoms in nicotine.
CH3..
2
:N-
1 :N
fentanyl
nicotine
2
3
A) localized
delocalized
localized
2
A)
sp?
B) delocalized
localized
localized
В)
Sp3
C) localized
delocalized
delocalized
C) sp?
Sp3
D) delocalized
delocalized
localized
D) sp?
sp?
E) delocalized
delocalized
delocalized
E) sp?
*1
*Contributors: (1) Starkey
Last updated January 2019
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