Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Question:**
Which of these would give a positive iodoform test?
**Structures:**
- **A:** Molecular structure resembling an aldehyde or ketone with the formula CH₃C(=O)CH₂CH₃.
- **B:** Molecular structure resembling a ketone with the formula CH₃C(=O)CH(CH₃)₂.
- **C:** Cyclic ether structure attached to an alkyl chain with hydroxyl group.
- **D:** Propanol structure with formula CH₃CH₂CH₂OH.
**Options:**
- ○ B
- ○ A
- ○ A and D
- ○ none of them
- ○ D
- ○ C
- ○ A, C, and D
**Analysis:**
The iodoform test is used for the detection of methyl ketones or secondary alcohols with a methyl group on the carbon bearing the hydroxyl group. This test is positive for structures containing a CH₃C=O or CH₃CH(OH) group.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1932ea18-1310-44c1-b1da-825fb09ef63f%2Fe3b638bb-2288-4b52-bcce-4e46d5882445%2Ffignfw5_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Question:**
Which of these would give a positive iodoform test?
**Structures:**
- **A:** Molecular structure resembling an aldehyde or ketone with the formula CH₃C(=O)CH₂CH₃.
- **B:** Molecular structure resembling a ketone with the formula CH₃C(=O)CH(CH₃)₂.
- **C:** Cyclic ether structure attached to an alkyl chain with hydroxyl group.
- **D:** Propanol structure with formula CH₃CH₂CH₂OH.
**Options:**
- ○ B
- ○ A
- ○ A and D
- ○ none of them
- ○ D
- ○ C
- ○ A, C, and D
**Analysis:**
The iodoform test is used for the detection of methyl ketones or secondary alcohols with a methyl group on the carbon bearing the hydroxyl group. This test is positive for structures containing a CH₃C=O or CH₃CH(OH) group.
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