3. O₂N - Give the products of the following reactions. Br Pd(PPh3)4 NaOEt TMSO Me₂CuLi Et2O, 0 °C NO2 Br Bu3Sn Ph Ph Pd(PPh3)4 LICI, DMF 50 °C, 24hr Br Pd(acac)2, Cul DMSO 125 °C, 24 hr Pd(OAc)2, K2CO3 DMF 135 °C, 5 hr
3. O₂N - Give the products of the following reactions. Br Pd(PPh3)4 NaOEt TMSO Me₂CuLi Et2O, 0 °C NO2 Br Bu3Sn Ph Ph Pd(PPh3)4 LICI, DMF 50 °C, 24hr Br Pd(acac)2, Cul DMSO 125 °C, 24 hr Pd(OAc)2, K2CO3 DMF 135 °C, 5 hr
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 75AP: Phenols (ArOH) are relatively acidic, and the presence of a substituent group on the aromatic ring...
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Transcribed Image Text:3.
O₂N
- Give the products of the following reactions.
Br
Pd(PPh3)4
NaOEt
TMSO
Me₂CuLi
Et2O, 0 °C
NO2
Br
Bu3Sn
Ph
Ph
Pd(PPh3)4
LICI, DMF
50 °C, 24hr
Br
Pd(acac)2, Cul
DMSO
125 °C, 24 hr
Pd(OAc)2, K2CO3
DMF
135 °C, 5 hr
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