Which of the following represents the correct graph for S2 reaction ? log (rate) (a) CHз - Br CHз - CH- Br CH3 - CH- Br CH CH CH3 -Ċ - Br ČH3 log( rate) (b) CH3 - Br i– Pr – Br Et – Br t- Bu – Br log (rate) (c) CH3 – Br Et – Br i- Pr – Br t- Bu – Br (isopropyl) log (rate) (d) CHз - Br Et- Br i- Pr – Br t– Bu – Br

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**Question 18: Which of the following represents the correct graph for the S<sub>N</sub>2 reaction?**

**Graph Descriptions:**

- **Graph (a):**
  - The vertical axis is labeled "log (rate)."
  - The horizontal axis lists bromides: CH<sub>3</sub>–Br, CH<sub>3</sub>–CH<sub>2</sub>–Br, CH<sub>3</sub>–CH–Br with a CH<sub>3</sub> group, and CH<sub>3</sub>–C–Br with two CH<sub>3</sub> groups.
  - The graph shows a decreasing curve, indicating a decline in the reaction rate with increasing steric hindrance.

- **Graph (b):**
  - The vertical axis is labeled "log (rate)."
  - The horizontal axis lists bromides: CH<sub>3</sub>–Br, Et–Br, i–Pr–Br, t–Bu–Br.
  - The graph is a straight line, indicating a constant reaction rate regardless of the substrate.

- **Graph (c):**
  - The vertical axis is labeled "log (rate)."
  - The horizontal axis lists bromides: CH<sub>3</sub>–Br, Et–Br, i–Pr–Br (isopropyl), t–Bu–Br.
  - The graph shows an increasing curve, suggesting that the reaction rate increases with increased steric hindrance.

- **Graph (d):**
  - The vertical axis is labeled "log (rate)."
  - The horizontal axis lists bromides: CH<sub>3</sub>–Br, Et–Br, i–Pr–Br, t–Bu–Br.
  - The graph shows a wavy pattern, suggesting no clear trend in reaction rate.

The correct graph for an S<sub>N</sub>2 reaction would likely be one that demonstrates decreased reaction rate with increased steric hindrance due to the backside attack mechanism of S<sub>N</sub>2 reactions.
Transcribed Image Text:**Question 18: Which of the following represents the correct graph for the S<sub>N</sub>2 reaction?** **Graph Descriptions:** - **Graph (a):** - The vertical axis is labeled "log (rate)." - The horizontal axis lists bromides: CH<sub>3</sub>–Br, CH<sub>3</sub>–CH<sub>2</sub>–Br, CH<sub>3</sub>–CH–Br with a CH<sub>3</sub> group, and CH<sub>3</sub>–C–Br with two CH<sub>3</sub> groups. - The graph shows a decreasing curve, indicating a decline in the reaction rate with increasing steric hindrance. - **Graph (b):** - The vertical axis is labeled "log (rate)." - The horizontal axis lists bromides: CH<sub>3</sub>–Br, Et–Br, i–Pr–Br, t–Bu–Br. - The graph is a straight line, indicating a constant reaction rate regardless of the substrate. - **Graph (c):** - The vertical axis is labeled "log (rate)." - The horizontal axis lists bromides: CH<sub>3</sub>–Br, Et–Br, i–Pr–Br (isopropyl), t–Bu–Br. - The graph shows an increasing curve, suggesting that the reaction rate increases with increased steric hindrance. - **Graph (d):** - The vertical axis is labeled "log (rate)." - The horizontal axis lists bromides: CH<sub>3</sub>–Br, Et–Br, i–Pr–Br, t–Bu–Br. - The graph shows a wavy pattern, suggesting no clear trend in reaction rate. The correct graph for an S<sub>N</sub>2 reaction would likely be one that demonstrates decreased reaction rate with increased steric hindrance due to the backside attack mechanism of S<sub>N</sub>2 reactions.
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