Which of the following reactions is/are consistent with Markovnikov's rule? Br (a) + HBr (b) HBr Br Br (c) + HBr

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Title: Understanding Markovnikov's Rule through Reaction Examples**

**Content:**

The following reactions illustrate concepts in organic chemistry, specifically the application of Markovnikov’s rule in the addition of Hydrogen Bromide (HBr) to alkenes. Markovnikov's rule states that in the addition of HX (where X is a halogen) to an alkene, the hydrogen atom will attach to the carbon with the greater number of hydrogen atoms (less substituted), while the halogen will attach to the carbon with fewer hydrogen atoms (more substituted).

---

**Reaction Diagrams:**

**(a) Reaction:**

- **Structure:** A cyclohexyl ethene reacting with HBr.
- **Product:** The product shows the bromine (Br) attached to the more substituted carbon of the previous double bond, consistent with Markovnikov’s rule.

**(b) Reaction:**

- **Structure:** Another cyclohexyl ethene isomer reacting with HBr.
- **Product:** Bromine attaches to the less substituted carbon in this case, which is inconsistent with Markovnikov's rule.

**(c) Reaction:**

- **Structure:** A different cyclohexene reacting with HBr.
- **Product:** The bromine is attached to the more substituted carbon of the alkene, consistent with Markovnikov’s rule.

---

**Summary:**

- **Reactions (a) and (c)** adhere to Markovnikov's rule, where the addition of HBr results in bromine attaching to the more substituted carbon of the double bond.
- **Reaction (b)** does not conform to Markovnikov’s rule as the bromine attaches to the less substituted carbon.

Understanding these reactions can help in predicting product outcomes in alkene reactions involving hydrogen halides.
Transcribed Image Text:**Title: Understanding Markovnikov's Rule through Reaction Examples** **Content:** The following reactions illustrate concepts in organic chemistry, specifically the application of Markovnikov’s rule in the addition of Hydrogen Bromide (HBr) to alkenes. Markovnikov's rule states that in the addition of HX (where X is a halogen) to an alkene, the hydrogen atom will attach to the carbon with the greater number of hydrogen atoms (less substituted), while the halogen will attach to the carbon with fewer hydrogen atoms (more substituted). --- **Reaction Diagrams:** **(a) Reaction:** - **Structure:** A cyclohexyl ethene reacting with HBr. - **Product:** The product shows the bromine (Br) attached to the more substituted carbon of the previous double bond, consistent with Markovnikov’s rule. **(b) Reaction:** - **Structure:** Another cyclohexyl ethene isomer reacting with HBr. - **Product:** Bromine attaches to the less substituted carbon in this case, which is inconsistent with Markovnikov's rule. **(c) Reaction:** - **Structure:** A different cyclohexene reacting with HBr. - **Product:** The bromine is attached to the more substituted carbon of the alkene, consistent with Markovnikov’s rule. --- **Summary:** - **Reactions (a) and (c)** adhere to Markovnikov's rule, where the addition of HBr results in bromine attaching to the more substituted carbon of the double bond. - **Reaction (b)** does not conform to Markovnikov’s rule as the bromine attaches to the less substituted carbon. Understanding these reactions can help in predicting product outcomes in alkene reactions involving hydrogen halides.
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Group 2 Elements
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY