Formal Charges
Formal charges have an important role in organic chemistry since this concept helps us to know whether an atom in a molecule is neutral/bears a positive or negative charge. Even if some molecules are neutral, the atoms within that molecule need not be neutral atoms.
Polarity Of Water
In simple chemical terms, polarity refers to the separation of charges in a chemical species leading into formation of two polar ends which are positively charged end and negatively charged end. Polarity in any molecule occurs due to the differences in the electronegativities of the bonded atoms. Water, as we all know has two hydrogen atoms bonded to an oxygen atom. As oxygen is more electronegative than hydrogen thus, there exists polarity in the bonds which is why water is known as a polar solvent.
Valence Bond Theory Vbt
Valence bond theory (VBT) in simple terms explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. It gives a quantum mechanical approach to the formation of covalent bonds with the help of wavefunctions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
Which of the following Lewis dot structures best represents carbon dioxide?
![**Carbon Dioxide Lewis Structures**
In the image, there are four Lewis structure representations labeled A, B, C, and D, each depicting a possible configuration of carbon dioxide (CO₂).
1. **Structure A:**
- The structure shows a linear arrangement with a carbon (C) atom in the center.
- There are two oxygen (O) atoms, one on each side of the carbon atom.
- Each oxygen atom forms a double bond with the carbon atom.
- The oxygen atoms each have two lone pairs of electrons, depicted by dots around them.
2. **Structure B:**
- This structure incorrectly depicts carbon dioxide.
- An oxygen atom is in the center, with a carbon atom double-bonded to it on each side.
- Each carbon atom has two lone pairs, which is not typical for CO₂.
3. **Structure C:**
- This similarly incorrect structure shows a linear arrangement.
- The carbon atom is at the center with a triple bond connected to an oxygen atom on either side.
- Each oxygen atom shows a single lone pair, which does not satisfy the typical valence of oxygen.
4. **Structure D:**
- This is another incorrect structure for carbon dioxide.
- It displays an oxygen atom in the center, triple-bonded to carbon atoms on either side.
- Each carbon atom has two lone pairs of electrons, contrary to typical valence structures.
**Analysis:**
- The correct Lewis structure for carbon dioxide is Structure A, which satisfies the octet rule for each atom involved and represents the actual bonding in CO₂.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc12fcdcc-9d0a-4fc7-beea-71e0d0ca0741%2F9b86239e-8a29-47bf-82d5-9128e22de6ac%2Fis6y6dl_processed.png&w=3840&q=75)
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