Which of the following cannot be an electrophile? Br Br

Introductory Chemistry: An Active Learning Approach
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ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
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Chapter21: Organic Chemistry
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Question 12
### Quiz: Electrophilicity in Organic Chemistry

**Question:**
Which of the following cannot be an electrophile?

**Options:**
1. ![Option 1: Ketone](https://via.placeholder.com/20)  
   Structure: A carbonyl group (C=O)
2. ![Option 2: Bromide Ion](https://via.placeholder.com/20)  
   Structure: Bromine with a negative charge (Br⁻)
3. ![Option 3: Alkyl Bromide](https://via.placeholder.com/20)  
   Structure: A bromine atom attached to an alkyl group
4. ![Option 4: Carbocation](https://via.placeholder.com/20)  
   Structure: A three-carbon chain with a positive charge on the central carbon

**Explanation of Diagrams:**

1. **Option 1:**
   - **Structure:** This represents a carbonyl group, typically found in ketones or aldehydes, where a carbon atom is double-bonded to an oxygen atom.
   
2. **Option 2:**
   - **Structure:** This depicts a bromide ion (Br⁻), where bromine carries a negative charge.
   
3. **Option 3:**
   - **Structure:** This shows an alkyl group attached to a bromine atom, illustrating an alkyl bromide.
   
4. **Option 4:**
   - **Structure:** This represents a carbocation, a three-carbon chain with a positive charge on the central carbon atom.

**Answer:**
In this question, the correct answer is Option 2: **Bromide ion (Br⁻)**. Bromide ions are nucleophiles due to their negative charge and the presence of a lone pair of electrons, which makes them electron-rich species that donate electrons rather than accept them, thus they cannot act as electrophiles.

### Key Concepts:
- **Electrophiles** are species that accept electron pairs. They are typically positively charged or have a partial positive charge.
- **Nucleophiles** are species that donate electron pairs. They are typically negatively charged or have a lone pair of electrons.

For detailed explanations and examples, please refer to the electrophilicity and nucleophilicity sections in your organic chemistry textbook.
Transcribed Image Text:### Quiz: Electrophilicity in Organic Chemistry **Question:** Which of the following cannot be an electrophile? **Options:** 1. ![Option 1: Ketone](https://via.placeholder.com/20) Structure: A carbonyl group (C=O) 2. ![Option 2: Bromide Ion](https://via.placeholder.com/20) Structure: Bromine with a negative charge (Br⁻) 3. ![Option 3: Alkyl Bromide](https://via.placeholder.com/20) Structure: A bromine atom attached to an alkyl group 4. ![Option 4: Carbocation](https://via.placeholder.com/20) Structure: A three-carbon chain with a positive charge on the central carbon **Explanation of Diagrams:** 1. **Option 1:** - **Structure:** This represents a carbonyl group, typically found in ketones or aldehydes, where a carbon atom is double-bonded to an oxygen atom. 2. **Option 2:** - **Structure:** This depicts a bromide ion (Br⁻), where bromine carries a negative charge. 3. **Option 3:** - **Structure:** This shows an alkyl group attached to a bromine atom, illustrating an alkyl bromide. 4. **Option 4:** - **Structure:** This represents a carbocation, a three-carbon chain with a positive charge on the central carbon atom. **Answer:** In this question, the correct answer is Option 2: **Bromide ion (Br⁻)**. Bromide ions are nucleophiles due to their negative charge and the presence of a lone pair of electrons, which makes them electron-rich species that donate electrons rather than accept them, thus they cannot act as electrophiles. ### Key Concepts: - **Electrophiles** are species that accept electron pairs. They are typically positively charged or have a partial positive charge. - **Nucleophiles** are species that donate electron pairs. They are typically negatively charged or have a lone pair of electrons. For detailed explanations and examples, please refer to the electrophilicity and nucleophilicity sections in your organic chemistry textbook.
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