Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:**Question 8:**
Which of the following alkyl halides undergo rearrangement in S<sub>N</sub>1 reaction?
- (a) A molecule with a structure:
- CH<sub>3</sub>
- |
- CH<sub>3</sub> - C - CH - CH<sub>3</sub>
- |
- CH<sub>3</sub> I
- (b) A cyclohexane ring with substituents:
- One chlorine (Cl) atom
- A methyl (CH<sub>3</sub>) group
- (c) A cyclohexane ring with one iodine (I) atom as a substituent.
- (d) All of these
**Diagrams Descriptions:**
- Diagram (a) represents a branched alkyl iodide with an iodine atom and three methyl groups.
- Diagram (b) represents a cyclohexyl chloride with one chlorine atom and one methyl group as substituents.
- Diagram (c) represents a cyclohexyl iodide with one iodine atom as a substituent.
In an S<sub>N</sub>1 reaction, carbocation rearrangement is possible, making the stability of the carbocation an essential factor in predicting rearrangement.
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