Which of the compounds below form water soluble salts (quantitatively) when added to a saturated aqueous sodium bicarbonate solution? Consider the pKa values of the functional groups and the acid/base strength of bicarbonate itself. OH „CO2H `OCH3 b. OH d. а. с.
Which of the compounds below form water soluble salts (quantitatively) when added to a saturated aqueous sodium bicarbonate solution? Consider the pKa values of the functional groups and the acid/base strength of bicarbonate itself. OH „CO2H `OCH3 b. OH d. а. с.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Question b:**
Which of the compounds below form water soluble salts (quantitatively) when added to a saturated aqueous sodium bicarbonate solution? Consider the \( pK_a \) values of the functional groups and the acid/base strength of bicarbonate itself.
**Compounds:**
- **a.** Benzoic acid \(\text{(C}_6\text{H}_5\text{CO}_2\text{H)}\)
- **b.** Hydroxymethoxybenzene \(\text{(OH attached to benzene with an OCH}_3\text{ group)}\)
- **c.** Pyridine with a piperidine ring
- **d.** 2-hydroxycyclohexanone \(\text{(a carbonyl and hydroxyl group on a cyclohexane ring)}\)
**Explanation of Diagrams:**
- **Compound a:** Shows a benzene ring with a carboxyl group (\(\text{CO}_2\text{H}\)) attached.
- **Compound b:** Displays a benzene ring with a hydroxyl group (\(\text{OH}\)) and a methoxy group (\(\text{OCH}_3\)).
- **Compound c:** Consists of a pyridine ring bonded to a secondary amine-containing ring (piperidine).
- **Compound d:** Features a cyclohexane ring with a ketone (\(=\text{O}\)) and a hydroxyl group (\(\text{OH}\)) positioned on adjacent carbons.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F32bb3717-a6fb-4f58-b035-9d5406559919%2F7495ef21-25b8-454c-80c3-a284d8f9cf8d%2Foki8evg_processed.png&w=3840&q=75)
Transcribed Image Text:**Question b:**
Which of the compounds below form water soluble salts (quantitatively) when added to a saturated aqueous sodium bicarbonate solution? Consider the \( pK_a \) values of the functional groups and the acid/base strength of bicarbonate itself.
**Compounds:**
- **a.** Benzoic acid \(\text{(C}_6\text{H}_5\text{CO}_2\text{H)}\)
- **b.** Hydroxymethoxybenzene \(\text{(OH attached to benzene with an OCH}_3\text{ group)}\)
- **c.** Pyridine with a piperidine ring
- **d.** 2-hydroxycyclohexanone \(\text{(a carbonyl and hydroxyl group on a cyclohexane ring)}\)
**Explanation of Diagrams:**
- **Compound a:** Shows a benzene ring with a carboxyl group (\(\text{CO}_2\text{H}\)) attached.
- **Compound b:** Displays a benzene ring with a hydroxyl group (\(\text{OH}\)) and a methoxy group (\(\text{OCH}_3\)).
- **Compound c:** Consists of a pyridine ring bonded to a secondary amine-containing ring (piperidine).
- **Compound d:** Features a cyclohexane ring with a ketone (\(=\text{O}\)) and a hydroxyl group (\(\text{OH}\)) positioned on adjacent carbons.
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