Which of the alcohols listed below would you expect to react most rapidly with PBr3?     (CH3CH2)2CH(OH)CH2CH3     CH3CH2CH2CH2CH2CH2OH     (CH3CH2)3COH     (CH3CH2)2CHOHCH3 1. (b) The conversion of 3-methyl-1-octanol to 1-bromo-3-methyloctane is best achieved through use of which of these reagents in a low temperature reaction?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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  1. (a) Which of the alcohols listed below would you expect to react most rapidly with PBr3?

       

    (CH3CH2)2CH(OH)CH2CH3

       

    CH3CH2CH2CH2CH2CH2OH

       

    (CH3CH2)3COH

       

    (CH3CH2)2CHOHCH3

    1. (b) The conversion of 3-methyl-1-octanol to 1-bromo-3-methyloctane is best achieved through use of which of these reagents in a low temperature reaction?

       

    Conc. HBr

       

    NaBr, H2SO4

       

    Br2

       

    PBr3

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