Which has a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer: trans-1,4-difluorocyclohexane or cis-1-tert-butyl-3- fluorocyclohexane? O trans-1,4-difluorocyclohexane O cis-1-tert-butyl-3-fluorocyclohexane
Which has a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer: trans-1,4-difluorocyclohexane or cis-1-tert-butyl-3- fluorocyclohexane? O trans-1,4-difluorocyclohexane O cis-1-tert-butyl-3-fluorocyclohexane
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:**Question:**
Which has a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer: trans-1,4-difluorocyclohexane or cis-1-tert-butyl-3-fluorocyclohexane?
**Options:**
- ○ trans-1,4-difluorocyclohexane
- ● cis-1-tert-butyl-3-fluorocyclohexane
**Explanation:**
This question explores the stability of different conformations of substituted cyclohexanes. In cyclohexane rings, substituents can either be in equatorial or axial positions. Generally, diequatorial conformers are more stable than diaxial conformers due to less steric hindrance. Here, the question asks which compound has a higher percentage of the more stable diequatorial conformation. The selected option is "cis-1-tert-butyl-3-fluorocyclohexane," indicating that this compound more often adopts the diequatorial conformation compared to the diaxial conformation.
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