Which compound or compounds dominate the product mixtures of the reaction shown?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Which compound or compounds dominate the product mixtures of the reaction
shown?
SO/H2SO4
(fuming)
CI.
CI
CI.
B.
SOH
2229
SO3H
CI.
C
Compound B
Compounds A and D
Compounds A and C
Compounds C and D
Transcribed Image Text:Which compound or compounds dominate the product mixtures of the reaction shown? SO/H2SO4 (fuming) CI. CI CI. B. SOH 2229 SO3H CI. C Compound B Compounds A and D Compounds A and C Compounds C and D
Expert Solution
Step 1 Electrophilic aromatic substitution reaction (EASR)

 

  • Benzene undergo EASR type reaction 
  • On simple benzene no selectivity , only one product is formed 
  • Where as di substituted benzene , product depends upon group which is substituted on benzene, Chlorine is weak ring deactivating group  , hence incoming electrophile is substituted at ortho and para position 

 

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