Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:### Title: SN2 Reaction Transition State Identification
#### Question:
Which choice shows the transition state for the given SN2 reaction?
#### Reaction Scheme:
- **Reactants:** Bromomethane (Br—CH₂CH₃) + Sodium cyanide (NaCN)
- **Products:** 2-Cyanopropane + Sodium bromide (NaBr)
#### Options:
- **I:** Shows a structure with Br and CN both bonded to a central carbon.
- **II:** Displays a trigonal bipyramidal transition state with NC and CH₂CH₃ having partial negative charges (δ-) and Br having a partial positive charge (δ+).
- **III:** Similar trigonal bipyramidal structure, but different geometric arrangement.
- **IV:** Linear structure between CN and CH₂CH₃.
#### Answer Choices:
- ○ III
- ○ II
- ○ IV
- ○ I
#### Explanation:
The SN2 reaction is characterized by the formation of a transition state where the nucleophile attacks the electrophile, leading to the simultaneous ejection of the leaving group. Look for the trigonal bipyramidal structure indicative of such a transition state.
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