When we study photochemical processes in the upper atmosphere, we need to know how frequently atoms and molecules collide. At an altitude of 20 km, T = 217 K and PN2 = 0.050 atm (for this problem, assume only nitrogen molecules are present). What is the mean free path of N2 at an altitude of km? ( = 0.43 nm2)

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
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  1. When we study photochemical processes in the upper atmosphere, we need to know how frequently atoms and molecules collide. At an altitude of 20 km, T = 217 K and PN2 = 0.050 atm (for this problem, assume only nitrogen molecules are present).

    1. What is the mean free path of N2 at an altitude of km? ( = 0.43 nm2)

    2. How many collisions per second does a N2 molecule make at an altitude of 20 km?

    3. What is the collision density, Z, under these conditions?

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