Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:6.51b
Explain the observed stereochemistry.
When the second intermediate is redrawn from the following perspective, it becomes clear that
O the electrons in the carbon-carbon-bond come from above the carbon-axygen x bond, allowing for the chirality center to be generated with the stereochemistry shown.
the electrons in the carbon-carbon-bond come from below the carbon-oxygen x bond, allowing for the chirality center to be generated with the stereochemistry shown.
the electrons in the carbon-exygen-bond come from below the carbon-cartion a bond, allowing for the chirality center to be generated with the stereochemistry shown.
the electrons in the carbon-exygen x-band come from above the carbon-carbon bond, allowing for the chirality center to be generated with the stereochemistry shown.
OO
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