When the reaction below reaches equilibrium, does the equilibrium lie on the left or the right side?  Briefly explain. ClO–  +  CH3CO2H  ⇌  HClO  +  CH3CO2–

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When the reaction below reaches equilibrium, does the equilibrium lie on the left or the right side?  Briefly explain.

ClO  +  CH3CO2H  ⇌  HClO  +  CH3CO2

 

When the terminal phosphate is cleaved from the adenosine triphosphate molecule, the products are adenosine diphosphate and inorganic phosphate,  ATP + H2O  ––>  ADP  +  Pi, where Pi stands for the various forms of phosphate that exist at the pH of the particular solution.  If the total concentration of Pi  is 2.5 x 10–2M, what are the concentrations of the predominant forms of phosphate that exist at pH 7.4?

 

 

  1. Permanganate, MnO4, can act as an oxidizing agent in both acidic and basic aqueous solutions. Balance each of the following reactions by the half–reaction method, showing all steps in the balancing process.

 

  1. MnO4   +   Al   ––>   MnO2   +   Al(OH)4                                in aqueous base

 

  1. MnO4   +   CH3COOH   ––>   Mn+2   +   CO2                            in aqueous acid

 

 

 

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