When the rate for the reaction 2NO+ 0 2 NO, was studied, the role was found to double when the O₂ concentration was doubled while the NO concentration was unchanged. It was also found that the rate quadruples when the NO concentration is doubled while the O, concentration is unchanged.
When the rate for the reaction 2NO+ 0 2 NO, was studied, the role was found to double when the O₂ concentration was doubled while the NO concentration was unchanged. It was also found that the rate quadruples when the NO concentration is doubled while the O, concentration is unchanged.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:When the rate for the reaction
2NO+ 0
2 NO,
was studied, the rate was found to double when the O₂ concentration was doubled while
the NO concentration was unchanged. It was also found that the rate quadruples when
the NO concentration is doubled while the O, concentration is unchanged.
o What is the rate law expression for this reaction? P
Two mechanisms were proposed for this reaction as shown below.
PROPOSAL I
Step 1:
Step 2:
NO + O₂
NO NO
PROPOSAL II
Step 1
Step 2
Step 3
NO NO
0₂ + N₂O₂
N₂0₂
NO:
NO,
N₂O₂
N₂O₁
NO₂
(fast)
NO, (alem, RDS)
(slow, RDS)
(test)
NO₂ (fast)
b. Write a predicted rate low for each proposed mechanism. In your predicted rate law,
make sure no intermediates are present in the overall expression
c. Which proposed mechanism I or II agrees with the rate kw expression that you
determined above? You must also explain your reasoning or no credit will be given Place
Expert Solution

Step 1
Note - Since the given question is a multiple question, hence I solved first question according to rules of bartleby. Please repost the rest question separately.
Here we have to predict the rate law expression of the following given reaction from the given experimental observation.
Step by step
Solved in 3 steps with 2 images

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